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Rates of reaction
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Cards (41)
What is the relationship between the frequency of successful collisions and the reaction rate?
The
greater
the frequency of successful collisions, the
greater
the reaction rate.
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What does the rate of a reaction measure?
The rate of a reaction measures how quickly a
reactant
is used up or a
product
is formed.
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What is required for a chemical reaction to occur according to collision theory?
Reactant particles must
collide
with each other and have enough
energy
to react.
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What is a successful collision?
A successful collision is a
collision
between
reactant
particles that has enough energy for a reaction to happen.
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What is activation energy?
Activation energy is the minimum amount of
energy
that
colliding particles
must have for them to react.
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How does the activation energy vary?
The activation energy is different for different reactions.
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What are the two equations to calculate the mean rate of reaction?
\(
mean
~rate~of~
reaction
= \frac{quantity~of~reactant~used}{time~taken}\)
\(
mean
~rate~of~
reaction
= \frac{quantity~of~product~formed}{time~taken}\)
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When is measuring mass a useful method in a reaction?
Measuring mass is useful when
carbon dioxide
is a product that leaves the
reaction container.
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What units are typically used for measuring the rate of reaction when measuring mass?
The units for rate are usually
g/s
or
g/min.
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How can the volume of a gas be measured during a reaction?
The volume of a gas can be measured using a
gas syringe
or an
upside-down burette.
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What units are typically used for
measuring
the rate of reaction when measuring volume?
The units for rate are usually
cm
3
^3
3
s
−
1
^{-1}
−
1
or cm
3
^3
3
min
−
1
^{-1}
−
1
.
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How can the rate of reaction be analyzed graphically?
Plot a
graph
of mass or
volume
of product formed against time.
The
steeper
the line, the
greater
the rate of reaction.
Faster
reactions finish sooner than
slower
reactions.
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What does the gradient of the line on a reaction rate graph represent?
The gradient of the line is
equal
to the rate of reaction; the steeper the line, the
greater
the rate of reaction.
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What happens to the line on a graph when a reaction is fast?
In fast reactions, the
line
becomes
horizontal
and finishes sooner than slower reactions.
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How can the rate of a chemical reaction be measured in higher education?
The rate of a chemical reaction can also be measured in
Mol
s
−
1
^{-1}
−
1
.
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What is the relationship between the frequency of successful collisions and the reaction rate?
The
greater
the frequency of successful collisions, the
greater
the reaction rate.
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What does the concentration of a solution indicate?
The
concentration
indicates how much of a substance is
dissolved
in water.
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How does increasing the concentration of a reacting solution affect the reaction rate?
Increasing the
concentration increases
the number of particles present, leading to more
collisions.
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What happens to the frequency of collisions when the pressure of a reacting gas is increased?
The frequency of collisions
increases
as the reactant particles become more
crowded.
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What is meant by a successful collision in a chemical reaction?
A successful collision is one that has enough
energy
for a
reaction
to occur.
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What does the mean energy of the particles refer to in a reaction?
The mean energy refers to the
average energy
of the
particles
in the system.
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How can the rates of two or more reactions be compared?
The rates can be compared using a
graph
of
mass
or volume of product formed against time.
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What do the curved red and green lines on a reaction graph represent?
The curved lines
represent
the reaction data for
two different reactions
over time.
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What does the steepness of a tangent on a reaction graph indicate?
The
steeper
the tangent, the
faster
the reaction is occurring.
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What happens to the steepness of the tangent as the reaction progresses?
The steepness of the tangent
decreases
, indicating that the reaction is
slowing down.
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How do you calculate the rate of reaction from the gradient of a tangent?
The rate of reaction is calculated using the equation:
r
a
t
e
o
f
r
e
a
c
t
i
o
n
=
rate~of~reaction =
r
a
t
e
o
f
re
a
c
t
i
o
n
=
c
h
a
n
g
e
i
n
m
a
s
s
o
r
v
o
l
u
m
e
o
f
p
r
o
d
u
c
t
c
h
a
n
g
e
i
n
t
i
m
e
\frac{change~in~mass~or~volume~of~product}{change~in~time}
c
han
g
e
in
t
im
e
c
han
g
e
in
ma
ss
or
v
o
l
u
m
e
o
f
p
ro
d
u
c
t
.
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What is the rate of reaction if the change in volume of product is 60 cm³ over 5 seconds?
The rate of reaction is
12
cm
3
/
s
12 \text{ cm}^3/\text{s}
12
cm
3
/
s
.
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What factors affect the rate of reaction?
Frequency
of successful collisions
Concentration
of reacting solutions
Pressure
of reacting gases
Surface area
to
volume
ratio
Temperature
Presence of
catalysts
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What are the key concepts related to rates of reaction?
Successful
collisions lead to reactions
Concentration
increases
collision frequency
Pressure
increases
collision frequency in gases
Tangents
on graphs indicate reaction rates
Rate of reaction can be calculated from
gradients
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What is a
catalyst
?
A
substance
that changes the rate of a chemical
reaction
without being changed by the reaction itself.
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How does a catalyst affect the rate of a reaction?
A catalyst increases the rate of a reaction by providing an
alternative
reaction pathway with
lower activation energy.
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What is activation energy?
The minimum amount of
energy
that
colliding
particles must have for them to react.
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What happens to the frequency of successful collisions when a catalyst is used?
The frequency of successful collisions
increases
because more particles have energy greater than the
activation
energy.
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How do catalysts appear in the overall chemical equation for a reaction?
Catalysts do
not
appear in the overall chemical equation for a
reaction.
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What is the role of enzymes in biological reactions?
Enzymes are proteins that catalyse or
speed
up
chemical reactions.
They are
specific
to particular reactions.
They
lower
the
activation energy
required for reactions.
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What is a
reaction
profile?
A chart showing how the
energy
of
reactants
and products changes during a reaction.
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What does a reaction profile illustrate regarding energy?
A reaction profile illustrates how the
energy
of the
reactants
and products changes during a reaction.
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What is the significance of the activation energy in a reaction profile?
The activation energy is
significant
because it determines the
minimum
energy required for a reaction to occur.
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How much mass of a catalyst is needed to increase the rate of a reaction?
Only a very
small
mass of catalyst is needed to
increase
the rate of a reaction.
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Why might not all reactions have suitable catalysts?
Not all reactions have suitable
catalysts
because different substances catalyse different
reactions.
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