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rate and extent of cc
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Cards (37)
What does the rate of reaction tell us?
It tells us how
quickly
reactants can be
converted
into
products.
Why is the fastest reaction not always the best in industry?
Because maximum
profit
reactions prioritize
cost
over the rate of
reaction.
What is the trade-off in reaction rates in industrial processes?
The
trade-off
is between
speed
,
cost
, and
safety.
How can you calculate the rate of reaction?
By calculating the
tangent's gradient.
What does collision theory explain?
It explains how
reactions
happen and why they occur at
different rates.
What is the minimum energy required for particles to react called?
Activation
energy.
How can the rate of reaction be increased according to collision theory?
By increasing the
collisions
or the
energy
of
reacting
particles.
What are the five main factors that affect the rate of reaction?
Catalysts
Concentration
of dissolved reactants
Pressure
of gaseous reactants
Surface
area
Temperature
How do catalysts affect activation energy?
Catalysts
decrease activation energy
and are not used up in the
reaction.
What is a key characteristic of catalysts in chemical reactions?
They find
alternative
reaction pathways to
lower activation energy.
Why do catalysts need cleaning or regenerating?
Because they can have
environmental downsides
in
energy
and
waste.
What are some examples of catalysts used in industry?
Iron
in the
Haber
process,
platinum
and
palladium
in
catalytic
converters, and
enzymes
in
biological
reactions.
Why are catalysts typically in powder form?
Because powders have the
highest
surface area for
reactions.
What are the advantages and disadvantages of using catalysts in industry?
Advantages:
Cost-effective
Reduces
combustion
of fossil fuels
Disadvantages:
Toxic
to the environment
Hard to
dispose
of and can
contaminate
What are reversible reactions?
Reactions where the
products
can
reform
the
reactants.
What does the equation A + B ⇌ C + D represent?
It represents a
reversible
reaction where
A
and
B
react to form
C
and
D
, and
C
and
D
can react to reform
A
and
B.
What is the relationship between exothermic and endothermic reactions in reversible reactions?
If the
forward
reaction is
exothermic
, the
backward
one will be
endothermic.
What does the conservation of energy state in reversible reactions?
The energy absorbed/released by the
forward
reaction will
equal
the amount of energy released/absorbed by the
backward
reaction.
What is dynamic equilibrium?
Dynamic equilibrium occurs when the
rates
of the
forward
and
backward
reactions are
equal.
What does the term 'dynamic' imply in dynamic equilibrium?
It implies that both the
forward
and
backward
reactions happen
simultaneously.
What happens to the concentrations of reactants and products at dynamic equilibrium?
The
concentrations
of the
reactants
and
products
do not
change
at
dynamic equilibrium.
What defines a closed system in the context of equilibrium?
A closed system is one where neither the
products
nor
reactants
can be
added
or
removed
, with no
external
factors acting on the
reaction.
How do changing conditions affect equilibrium?
Changing conditions alters the amounts of
products
and
reactants
at equilibrium, affecting the
position
of the equilibrium.
What is Le Chatelier’s principle?
Le Chatelier’s principle states that a
closed system
at
dynamic equilibrium
will
counteract
any
change
applied to it.
What factors can change the equilibrium position?
Temperature
Pressure
(only affects gaseous reactions)
Concentration
What happens to the equilibrium position when temperature is increased?
An increase in temperature favors the
endothermic
reaction, increasing
endothermic
products and decreasing
exothermic
products.
What occurs when the temperature is decreased in a reaction at equilibrium?
A decrease in temperature favors the
exothermic
reaction, increasing
exothermic
products and decreasing
endothermic
products.
How does an increase in pressure affect gaseous reactions at equilibrium?
An
increase
in pressure favors the
reaction
that produces
fewer
gas molecules to
reduce
pressure.
What is the
Haber process
used for?
Making
ammonia
for ammonium fertilizers
Why is the
Haber process
considered one of the world's most important reactions?
It helps reintroduce
nitrogen
into the soil
What is the balanced chemical equation for the
Haber process
?
N2
(g) + 3H2(g) ⇌ 2NH3(g)
What is the enthalpy change for the forward reaction in the
Haber process
?
-92
kJ/mol
What is the
enthalpy change
for the backward reaction in the
Haber process
?
+92
kJ/mol
What pressure is used in the
Haber process
, and why?
200 ATM
pressure favors the production of
ammonia
What
temperature
is maintained in the
Haber process
, and what is its effect?
450
°C provides enough
kinetic
energy
but favors the
backward
reaction
What type of catalyst is used in the
Haber process
?
Iron
catalyst
What happens to
N2
and
H2
in the
Haber process
?
Compressed
Heated
Condensed
Reused
Liquid ammonia
leaves the reaction basin