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Physical I
Kinetics
Maxwell-Boltzmann distribution
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Cards (34)
What does the Maxwell-Boltzmann distribution illustrate?
It shows the distribution of
kinetic energy
among gas particles.
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What does the area under the Maxwell-Boltzmann curve represent?
The area under the curve represents the
total number
of molecules.
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How does temperature affect the rate of reaction according to the video?
Higher temperatures increase the average
kinetic energy
of
particles
,
leading
to more
frequent
and
energetic
collisions.
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What happens to the Maxwell-Boltzmann distribution curve when temperature is decreased?
The
curve shifts to the
left
,
indicating
fewer
particles
have energy greater than the activation energy.
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Why do reactions occur faster at higher temperatures?
Particles
move
more
and
collide
more
often due to
increased
kinetic energy
.
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What effect does increasing pressure have on the rate of reaction?
Increasing pressure
increases
the
frequency
of
collisions
between
particles.
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How does concentration affect the rate of reaction?
Higher concentration means more
particles
in the same
volume
,
leading
to more
frequent
collisions
.
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What is the role of a catalyst in a reaction?
A catalyst
increases
the rate of
reaction
by
providing
an
alternative
pathway
with lower
activation energy
.
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How does a catalyst affect the Maxwell-Boltzmann distribution curve?
A catalyst shifts the
activation energy
line to the left,
increasing
the
area
of
particles
with
sufficient
energy
to
react.
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What is the significance of the area under the activation energy curve when a catalyst is present?
The
area
under the
activation
energy
curve
increases
, indicating
more
particles
have
sufficient
energy
to
react.
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What is one method to measure the rate of
reaction
involving a
precipitate
?
Timing
how long it takes for a
precipitate
to form
in
a
reaction.
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What is a limitation of using the
disappearing cross method
to measure
reaction rate
?
It can be
difficult
to
determine
exactly
when
the cross has
disappeared,
leading to errors.
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How can mass loss be used to measure the rate of a reaction?
By measuring the decrease in
mass
as
gas
is
produced
during the
reaction.
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What equipment can be used to measure the volume of gas produced in a reaction?
A gas
syringe
can be used to measure the
volume
of gas produced.
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What should be done when measuring gas produced over a specific period of time?
The experiment should be
repeated
using
different
conditions,
such as changing
temperature
or using a
catalyst
.
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What are the key factors that affect the rate of reaction?
Temperature
Concentration
Pressure
Presence of
catalysts
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How does a catalyst affect the energy profile of a reaction?
Lowers the
activation energy
Provides an
alternative
pathway
for the
reaction
Remains chemically
unchanged
after the reaction
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What are the methods to measure the rate of reaction?
Timing the formation of a
precipitate
Measuring
mass loss
for gas production
Measuring the
volume
of gas produced using a
gas syringe
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What is the fundamental requirement for a chemical reaction to occur according to collision theory?
Particles must collide with energy greater than or equal to the
activation energy
.
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What role does particle orientation play in chemical reactions?
Correct particle orientation is necessary for a successful
collision
to lead to a reaction.
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What are the reaction conditions that can impact the rate of a chemical reaction?
Temperature
Concentration
Pressure
Presence of
catalysts
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What is the Maxwell-Boltzmann distribution?
It is a pattern that describes the distribution of energies among molecules in a substance.
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What happens to the Maxwell-Boltzmann distribution when reaction conditions are changed?
The
shape
of the
curve
alters,
affecting the
number
of
particles
with
energy
greater
than the
activation
energy.
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What does the total area under the Maxwell-Boltzmann distribution curve represent?
It represents the
total number
of molecules in the sample.
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How does heating a substance affect its molecules?
It transfers
thermal energy
, converting it to
kinetic energy
, causing
molecules
to
move
faster
and
further.
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What is the effect of increased molecular movement on reaction rates?
Increased
movement
leads to
more
frequent
and
energetic
collisions
,
resulting
in a
higher
reaction
rate.
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What happens to the Maxwell-Boltzmann distribution at increased temperatures?
It
shifts
to the
right,
increasing
the
proportion
of
molecules
with
energy
greater
than
or
equal
to the
activation energy
.
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What occurs when the concentration of a sample is increased?
More
molecules
are
present
in the
same
volume,
leading
to more likely
collisions
.
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How does increasing pressure affect molecular collisions?
It
packs
molecules
closer
together,
increasing
the
likelihood
of
collisions.
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What is the effect of catalysts on reaction rates?
A catalyst
increases
the
rate
of
reaction
without
being
consumed
by providing an
alternative
reaction
path
with lower
activation energy
.
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How does the Maxwell-Boltzmann distribution curve change with the presence of a catalyst?
The
shape
remains
unchanged,
but the
position
of the
activation energy
shifts
to the
left.
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Why is it important that the total area under the Maxwell-Boltzmann curve remains constant?
It ensures that the total number of
molecules
in the sample does not change.
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What happens to the maxwell-boltzman distribution curve when temperature increases
Curve
shifts
to the
right
Peak
is
lower
Area
under
curve
is the
same
Area
under
curve
beyond
activation
energy
increases
What happens to Maxwell-Boltzmann Distribution curve when temperature decreases
Curve
shifts to the
left
Peak
is
higher
Area
under
curve
is the
same
Area
under
curve
beyond
activation
energy
decreases