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OCR A ALEVEL CHEMISTRY
module 3
reaction rates
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Cards (65)
What does the rate of reaction refer to?
The change in concentration or amount of a reactant or product per unit time.
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How is the rate of reaction calculated?
By dividing the amount of reactant used or product made by time.
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What must happen for a reaction to occur according to collision theory?
Particles must collide in the right direction and have sufficient kinetic energy.
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What is activation energy?
The minimum amount of energy required for a reaction to occur.
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What does an energy profile diagram show?
Changes in energy during a reaction, including activation energy.
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How does the shape of the energy profile relate to activation energy?
A flatter dome indicates lower activation energy is needed for the reaction.
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What does the Maxwell-Boltzmann distribution illustrate?
The distribution of
kinetic energy
among gas particles.
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What does the area under the Maxwell-Boltzmann curve represent?
The total number of molecules in the sample.
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What is the difference between the most likely energy and the mean energy of particles?
The most likely energy is the
peak
of the
distribution
, while the mean
energy
is the
average
energy of all
particles.
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How does temperature affect the rate of reaction?
Higher temperatures increase the average
kinetic energy
of
particles
, leading to more frequent and energetic collisions.
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What happens to the Maxwell-Boltzmann distribution when temperature is increased?
The curve shifts to the right, and the area beyond the
activation energy
increases.
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What occurs when the temperature is decreased in a reaction?
A smaller
proportion
of molecules will have energy greater than the
activation energy
.
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Why do reactions occur faster at higher temperatures?
Particles
move more quickly, collide more often, and have more
energetic
collisions.
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How does pressure affect the rate of reaction?
Increasing pressure brings
particles
closer together, leading to more frequent
collisions
.
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How does concentration affect the rate of reaction?
Higher concentration increases the
likelihood
of
collisions
between particles.
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What is a catalyst?
A substance that increases the rate of
reaction
without being consumed in the process.
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How do catalysts lower activation energy?
By providing an alternative
pathway
for the reaction.
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What is a heterogeneous catalyst?
A catalyst that is in a different
phase
from the reactants.
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What is the Haber process used for?
Manufacturing
ammonia
from
nitrogen
and
hydrogen
gases.
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Why is the use of catalysts important in industrial processes?
They speed up
reactions
, saving time and reducing costs.
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What is the role of zeolite as a catalyst?
It increases the
surface area
for reactions to occur more quickly.
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What are the key factors affecting the rate of reaction?
Temperature
Pressure
Concentration
Presence of
catalysts
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What are the types of catalysts?
Homogeneous
catalysts: same phase as reactants
Heterogeneous
catalysts: different phase from reactants
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What is the significance of activation energy in chemical reactions?
Minimum energy required for a reaction to occur
Determines the
rate of reaction
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How does the Maxwell-Boltzmann distribution relate to reaction rates?
Shows the distribution of kinetic energy among particles
Indicates the proportion of particles with energy greater than
activation energy
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How does increasing temperature affect the Maxwell-Boltzmann distribution?
Shifts the curve to the right
Increases the area beyond
activation energy
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How does increasing concentration affect reaction rates?
Increases the likelihood of
collisions
Leads to a higher chance of reaction
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How does increasing pressure affect reaction rates?
Brings
particles
closer together
Increases frequency of
collisions
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What is the relationship between catalysts and activation energy?
Catalysts lower activation energy
Provide an alternative
pathway
for reactions
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What is the importance of catalysts in industrial chemistry?
Speed up
reactions
Reduce costs and energy consumption
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What is the role of zeolite in catalysis?
Solid catalyst with
microscopic
pores
Increases surface area for reactions
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What are the tiny microscopic pores in catalysts called?
Micropores
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How do micropores affect the surface area of a catalyst?
They
increase
the
surface area
, allowing
reactions
to happen
quicker.
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What is a zeolite?
A type of
catalyst
with a large surface area due to
micropores
.
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What are the two types of catalysts?
Homogeneous
catalysts: same phase as reactants.
Heterogeneous
catalysts: different phase from reactants.
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What does "heterogeneous" mean in the context of catalysts?
It means the catalyst is in a different
phase
from the reactants.
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What is the Haber process used for?
It is used for the manufacturing of
ammonia
.
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What type of catalyst is used in the Haber process?
An
iron catalyst
.
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How does a heterogeneous catalyst speed up a reaction?
It provides an
alternative pathway
for the reaction.
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How can the surface area of a solid catalyst be increased?
By
grinding
it into a powder.
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