Kinetics

Cards (26)

  • What must happen for a reaction to occur according to collision theory?
    Particles must collide.
  • How is the rate of reaction defined?
    Rate is the change in concentration or amount of a reactant or product per unit time.
  • What is the formula for calculating the rate of reaction?
    Rate = amount of reactant used or product made / time
  • Why do most collisions between particles not lead to a reaction?
    Most collisions do not have the correct orientation or sufficient energy.
  • What is activation energy?
    It is the minimum amount of energy required for a reaction to occur.
  • How can activation energy be represented visually?
    Through an energy profile diagram showing the energy change from reactants to products.
  • What does the activation energy represent on an energy profile diagram?
    It is the difference between the energy of the reactants and the peak of the reaction profile line.
  • How does a low activation energy affect a reaction?
    It requires less energy to break bonds and initiate the reaction.
  • What does the Maxwell-Boltzmann distribution illustrate?
    It shows the energy distribution of gas particles.
  • What does the peak of the Maxwell-Boltzmann distribution represent?
    The most likely energy of a particle in a sample.
  • How does temperature affect the rate of reaction?
    Higher temperatures increase the average kinetic energy of particles, leading to more frequent and energetic collisions.
  • What happens to the Maxwell-Boltzmann distribution curve when temperature is increased?
    The curve shifts to the right, indicating more particles have energy greater than the activation energy.
  • What is the effect of decreasing temperature on the rate of reaction?
    A smaller proportion of molecules will have energy greater than the activation energy, leading to a slower reaction rate.
  • How does concentration affect the rate of reaction?
    Higher concentration increases the number of particles in a given volume, leading to more frequent collisions.
  • What role do catalysts play in chemical reactions?
    Catalysts increase the rate of reaction by providing an alternative pathway with lower activation energy.
  • What is an example of a catalyst mentioned in the video?
    Zeolite
  • How does a catalyst affect the Maxwell-Boltzmann distribution curve?
    It shifts the activation energy line to the left, increasing the area of particles with sufficient energy to react.
  • What is one method to measure the rate of reaction involving a precipitate?
    Timing how long it takes for a precipitate to form and obscure a marked cross.
  • What is a limitation of measuring the rate of reaction using the disappearing cross method?
    It can be difficult to determine exactly when the cross has disappeared, leading to errors.
  • How can mass loss be used to measure the rate of reaction?
    By measuring the decrease in mass as gas is produced during the reaction.
  • What equipment can be used to measure the volume of gas produced in a reaction?
    A gas syringe can be used to measure the volume of gas produced over time.
  • What are the factors affecting the rate of reaction?
    • Temperature
    • Concentration
    • Pressure
    • Catalysts
  • What is the relationship between temperature and reaction rate?
    • Higher temperature increases kinetic energy
    • More frequent and energetic collisions
    • Small increases in temperature lead to large increases in reaction rate
  • How does concentration affect the likelihood of collisions?
    • Higher concentration means more particles in a given volume
    • Increased chance of collisions
    • Higher chance of reaction
  • What is the role of a catalyst in a chemical reaction?
    • Provides an alternative pathway with lower activation energy
    • Increases the rate of reaction
    • Remains chemically unchanged after the reaction
  • How can the rate of reaction be measured experimentally?
    • Timing the formation of a precipitate
    • Measuring mass loss for gas production
    • Measuring gas volume using a gas syringe