Most elements are made up of atoms of different isotopes (e.g chlorine contains both ³⁵Cl and ³⁷Cl atoms)
The relative atomic mass (Ar) of an element is an average of the mass of the isotope taking into account the relative abundance of each isotope
Relative Atomic Mass, Ar is the average mass of an atom of an element relative to 1/12th mass of C¹²
Relative formula mass, Mr if referring specifically to a molecule (relative molecular mass) the average mass of a molecule of a substance relative to 1/12th the mass of C¹²
Relative formula mass, Mr more generally for any substance the sum of the relative atomic masses of all the atoms in the formula of a substance