One mole of anything contains 6.022×10²³ of those things. One mole of bananas is 6.022×10²³ bananas. One mole of water molecules is 6.022×10²³ water molecules
6.022×10²³ is known as the avogadro constant (=6.022×10²³mol-1)
The avogadro number was chosen so that the mass of one mole of particles of a substance equals the Mr in grams. For example, the Mr of water is 18.0 and the mass of one mole of water molecules in 18.0 grams