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CHEMISTRY
PHYSICAL CHEMISTRY I
Equilibria-NOTES
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Cards (25)
What is a reversible reaction?
A reaction where
reactants
form products that can reform the
original
reactants
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How is a reversible reaction represented?
Using a
double arrow
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What characterizes the endothermic and exothermic reactions in a reversible system?
One reaction is
endothermic
and the opposite is
exothermic
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What is dynamic equilibrium in reversible reactions?
It is when the
forward
and
backward
rate of reaction is the same
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What happens to the concentrations of reactants and products at dynamic equilibrium?
The concentrations remain
constant
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In what type of system does dynamic equilibrium occur?
In
closed systems
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What does Le Chatelier’s Principle predict?
How an
equilibrium
mixture will change if reaction conditions are altered
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What does Le Chatelier’s Principle state about a system subject to change?
The
system
will
alter
to
lessen
the
effect
of that
change
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How can Le Chatelier’s Principle be useful in industry?
It helps to maximize the
yield
of a desired product
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What effect does increasing temperature have on an endothermic reaction?
It favors the endothermic reaction and increases the
yield
of endothermic products
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What happens when temperature is decreased in an exothermic reaction?
It favors the exothermic reaction and increases the
yield
of exothermic products
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What is the effect of increasing pressure in a reaction?
It favors the side with fewer
moles
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What is the effect of decreasing pressure in a reaction?
It favors the side with more
moles
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How does increasing the concentration of reactants affect the reaction?
It favors the reaction that produces the
products
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What happens when the concentration of products is decreased?
It favors the reaction that reforms the
reactants
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How do catalysts affect the equilibrium position?
Catalysts
do
not
affect the
equilibrium position
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What do catalysts do in a reaction?
They allow
equilibrium
to be reached faster
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What does the equilibrium constant \( K_c \) indicate?
The position of equilibrium for a reaction at a certain
temperature
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When does the value of \( K_c \) change?
When the
reaction conditions
change
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How is \( K_c \) calculated?
By dividing the
concentration
of
products
by the concentration of
reactants
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What happens to the number of moles in the \( K_c \) expression?
Each substance is raised to a
power
equal to the number of moles
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How does the equilibrium constant's units vary?
The units depend on the
chemical reaction
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What affects the value of \( K_c \)?
Changing the reaction
temperature
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What does the value of \( K_c \) not change with?
Concentration change or use of a
catalyst
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What is the relationship between temperature and the equilibrium position?
Changing temperature results in different concentrations of
reactants
and products
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