particle model of matter

Cards (31)

  • density: amount of mass per unit volume
  • density
    there is little difference between the desnity of a solid and its corresponding liquid, this is because both are tightly packed
    the same number of particles in a gas, with the same volume to cover, will spread further apart
    > less dense than its corresponding solid and liquid
  • density calculations
    density = mass / volume
    it can be measures in either (g/cm^3) or (kg/m^3)
  • required practical - density
    volume
    volume can be measured by measuring the shape, and if irregular, by measuring the displacement
    1. measure the mass of the object
    2. fill a eurika can with water, up to the brim of the spout
    3. place a beaker under the spout to catch displaced water
    4. lower object in (on string)
    5. pour the displaced water into measuring cylinder
    6. measure the volume
  • changes of state
    boiling - active process, because you have to put (internal) energy into the liquid to turn it into a gas
    evaporation - passive process, because the liquid absorbs energy from the surroundings, so some of its particles gain enough energy to escape from the liquid
    both of these are liquid to gas, just done differently
  • changes of state are physical processes because they can be reversed and no new products are formed
  • internal energy
    when a material is heated or cooled, two things happen:
    • chemical bonds may form, break or stretch
    • there is a change in the chemical potential energy
    • as the material heats or cools, the particles will speed up or slow down
    • there is a change in the thermal energy store
  • the internal energy is the total amount of kinetic energy and chemical potential energy
  • internal energy
    When the substance melts or boils, energy is put in to breaking the bonds that are holding particles together, which increases the potential energy
  • internal energy
    the law of conservation means (assuming no energy is lost to the surroundings), energy will be transferred between the chemical store and the thermal store of the internal energy
  • energy is linked to the temperature of the material, but they are very different:
    • internal energy: the measure of the total energy of all the particles in a substance, this includes the kinetic energy of the particles and the chemical potential energy of the bonds between them
    • temperature: a measure of the average speed of the particles, it is based on the kinetic energy of the individual particles
  • when heating a substance
    takes more energy to raise the temperature of a larger substance, because more particles have changed speed
  • specific heat capacity: the amount of energy needed to increase 1kg of substance by 1.C
    the specific heat capacity of water is 4,200J
  • specific heat capacity
    the amount of energy stored or released by a substance can be calculated using the formula:
    ΔE = m c ∆θ
    change in thermal/internal energy (J) = mass(kg) x SHC(J/kg'C) x change in temperature ('C)
  • specific latent heat
    changing the internal energy of a material causes it to change temperature or state:
    • energy required for a particular change in temperature is given by the specific heat capacity
    • energy required for a particular change in state is given by the specific latent heat
  • specific latent heat
    specific latent heat: the amount of energy required to change the state of 1kg of substance without changing its temperature
    > the energy is used to change the state rather than increasing the kinetic energy and temperature
  • specific latent heat, of fusion and of vaporisation
    • latent heat of fusion: the amount of energy required to melt or freeze the material at its melting point
    • to do with liquids and solids
    • latent heat of vaporisation: the amount of energy required to boil or condense the material at its boiling point
    • to do with liquids and gases
  • calculating thermal energy changes
    ΔE = m x l
    change in thermal energy (J) = mass (Kg) x specific latent heat (J/Kg)
  • heating and cooling graphs
    the horizontal line is where energy is not being used to increase the speed or temperature of the particles, but instead is being used to break the bonds between the particles and change the state
    the longer the horizontal line, the more energy is used to cause the change of state
    the amount of energy represented by the horizontal lines is equal to the latent heat
  • If a change in internal energy of a material will cause it to change temperature and change state, both equations can be used.
  • particle motion
    particles in a gas move quickly and in all directions
    the speeds of the individual particles vary, but overall they move quicker than they do in solids or liquids
    > doesn't take long for gas particles to spread out and fill a container
  • gas pressure
    gas particles move quickly and in all directions
    > collide frequently (between particles or walls)
    the force acting on the container due to these collisions is at right angles to the container....
  • calculating pressure caused by a gas
    p = F / a
    pressure(N/m^2) = force(N) / area(m^2)
  • pressure and temperature
    the pressure of a gas will increase as its temperature increases, i the volume of the gas and the container stays the same.
    temperature is a measure of the average kinetic energy of its particles
    if the temperature is increased
    the particles will gain more kinetic energy, collide more frequetly, and with more force
    as the temperature increases, the pressure increases
    > pressure is directly proportional to temperature
  • pressure and volume
    as the volume decreases the pressure increases (ie: if you squeeze a balloon)
  • pressure and volume
    robert boyle first investigated the relationship between pressure and volume
    his experiment gave one of the first peices of experiemental evidence for particle theory
    he poured mercury into a J - shaped tube which was sealed at one end
    he was able to trap an air bubble
    he then poured in more mercury slowly
    he saw that the greater the volume of mercury, the more pressure the air bubble was experiencing, and the smaller the bubble became
    boyle showed that volume is inversely proportional to pressure
  • the pressure of a gas increases if the volume of the container deacreases, if the temperature remains the same
  • for a fixed mass of gas at a constant temperature:
    p V = constant
    pressure (Pa - pascals) x volume(m^3) = constant
  • The change in volume or pressure for gas at a constant temperature can be calculated using the equation:
    𝑝1𝑉1=𝑝2𝑉2
    p1 and V1 are the pressure and volume before either are changed, p2 and V2 are the pressure and volume after the change.
  • pressure can be increased by:
    • increasing the temperature - increases the force of each collision
    • decreasing the volume - increases the number of collisions per second
    boyle concluded that the volume could only be inversly proportional to the pressure for a fixed mass of gas and a constant temperature
    and only if the gas contained particles which were moving
    this led to a discovery which triggered the industrial revolution
  • forces applieed to the particles in a gas result in an energy transfer
    Since the volume of the gas has decreased, the pressure increases because the particles are moving in less space and collide more often. The temperature of the gas is not fixed in most applications and the increased pressure leads to an increase in temperature.