ALKENES

Cards (99)

  • What is an alkene?
    A hydrocarbon with a carbon-carbon double bond
  • What does it mean for an alkene to be unsaturated?
    It contains a carbon-carbon double bond
  • What is the general formula for alkenes?
    C<sub>n</sub>H<sub>2n</sub>
  • Which alkene has the formula C<sub>2</sub>H<sub>4</sub>?
    Ethene
  • How can you test for unsaturation in alkenes?
    Using bromine water
  • What color change indicates the presence of an alkene when using bromine water?
    From orange to colorless
  • What is the structure of an alkene like?
    Planar around the carbon-carbon double bond
  • What is restricted rotation in alkenes?
    Limited twisting around the carbon-carbon double bond
  • What type of isomerism is associated with alkenes due to restricted rotation?
    Geometric isomerism (E/Z isomerism)
  • What is stereoisomerism?
    Isomerism with different spatial arrangements
  • What is the difference between E and Z isomers?
    E isomers are on opposite sides
  • What does the term "CIS" refer to in isomerism?
    Groups on the same side of the double bond
  • What does the term "trans" refer to in isomerism?
    Groups on opposite sides of the double bond
  • How do you determine if an alkene has E/Z isomerism?
    Check if groups are on the same or opposite sides
  • What is the significance of having different priority groups in E/Z isomerism?
    It helps in naming the isomers correctly
  • What is the simplest alkene with no stereoisomerism?
    Ethene
  • Why does but-2-ene exhibit E/Z isomerism?
    It has different groups on each carbon of the double bond
  • What is the relationship between E/Z isomerism and the presence of hydrogen atoms?
    Hydrogens must be on different carbons
  • How do you name the isomers based on their configuration?
    Use Z or E before the alkene name
  • What is the importance of understanding E/Z isomerism in chemistry?
    It affects chemical properties and reactivity
  • What is the term used for isomers with different spatial arrangements of atoms?
    Stereoisomers
  • How do you determine the naming of isomers based on their groups?
    By identifying highest priority groups
  • If a carbon is double bonded to another carbon with various substituents, what should you look for to name it?
    Highest priority groups on each side
  • What is the significance of relative atomic mass in determining priority groups?
    It helps identify the highest priority substituents
  • Which element has the highest relative atomic mass in the example given?
    Bromine
  • What does it mean if the highest priority groups are on the same side of a double bond?
    It indicates a Z isomer
  • What does it mean if the highest priority groups are on opposite sides of a double bond?
    It indicates an E isomer
  • What is the first step in determining the priority of groups attached to a carbon?
    Identify the largest relative atomic mass
  • What is the CIP priority rule used for?
    To determine the priority of substituents
  • How would you identify the Z isomer of a compound?
    By ensuring highest priority groups are together
  • Why might a question about priority groups be tricky in an exam?
    Because of similar atomic numbers in groups
  • What is the atomic mass of chlorine?
    35.5
  • What is the significance of restricted rotation around a double bond?
    It allows for stereoisomer formation
  • How do you draw the structure of E and Z stereoisomers for hex-3-ene?
    Focus on the double bond and substituents
  • What is the structural formula for hex-3-ene?
    C6H10
  • What does the term "highest priority group" refer to in stereochemistry?
    The group with the largest atomic mass
  • How can you differentiate between E and Z isomers when drawing structures?
    By checking the position of highest priority groups
  • What is the feature of the double bond that causes stereoisomerism?
    Restricted rotation
  • What is the importance of knowing the E/Z nomenclature in organic chemistry?
    It helps in identifying stereoisomers
  • How do you determine the E or Z configuration for 3-methylpent-2-ene?
    By analyzing the substituents across the double bond