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CHEMISTRY
ORGANIC I
ALKENES
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Cards (99)
What is an alkene?
A
hydrocarbon
with a
carbon-carbon double bond
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What does it mean for an alkene to be unsaturated?
It contains a
carbon-carbon double bond
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What is the general formula for alkenes?
C<sub>n</sub>
H<sub>2n</sub>
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Which alkene has the formula C<sub>2</sub>H<sub>4</sub>?
Ethene
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How can you test for unsaturation in alkenes?
Using
bromine
water
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What color change indicates the presence of an alkene when using bromine water?
From
orange
to
colorless
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What is the structure of an alkene like?
Planar around the
carbon-carbon double bond
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What is restricted rotation in alkenes?
Limited twisting around the
carbon-carbon double bond
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What type of isomerism is associated with alkenes due to restricted rotation?
Geometric isomerism
(
E/Z isomerism
)
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What is stereoisomerism?
Isomerism with different
spatial
arrangements
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What is the difference between E and Z isomers?
E isomers are on
opposite
sides
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What does the term "CIS" refer to in isomerism?
Groups on the same side of the
double bond
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What does the term "trans" refer to in isomerism?
Groups on opposite sides of the
double bond
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How do you determine if an alkene has E/Z isomerism?
Check if groups are on the
same
or
opposite
sides
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What is the significance of having different priority groups in E/Z isomerism?
It helps in naming the
isomers
correctly
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What is the simplest alkene with no stereoisomerism?
Ethene
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Why does but-2-ene exhibit E/Z isomerism?
It has different groups on each carbon of the
double bond
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What is the relationship between E/Z isomerism and the presence of hydrogen atoms?
Hydrogens must be on different
carbons
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How do you name the isomers based on their configuration?
Use
Z
or
E
before the
alkene
name
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What is the importance of understanding E/Z isomerism in chemistry?
It
affects
chemical
properties
and
reactivity
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What is the term used for isomers with different spatial arrangements of atoms?
Stereoisomers
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How do you determine the naming of isomers based on their groups?
By identifying highest
priority
groups
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If a carbon is double bonded to another carbon with various substituents, what should you look for to name it?
Highest
priority groups
on each side
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What is the significance of relative atomic mass in determining priority groups?
It helps identify the highest priority
substituents
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Which element has the highest relative atomic mass in the example given?
Bromine
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What does it mean if the highest priority groups are on the same side of a double bond?
It indicates a
Z isomer
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What does it mean if the highest priority groups are on opposite sides of a double bond?
It indicates an
E isomer
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What is the first step in determining the priority of groups attached to a carbon?
Identify the
largest
relative atomic mass
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What is the CIP priority rule used for?
To
determine
the
priority
of
substituents
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How would you identify the Z isomer of a compound?
By ensuring
highest priority groups
are together
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Why might a question about priority groups be tricky in an exam?
Because of similar
atomic numbers
in groups
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What is the atomic mass of chlorine?
35.5
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What is the significance of restricted rotation around a double bond?
It allows for
stereoisomer
formation
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How do you draw the structure of E and Z stereoisomers for hex-3-ene?
Focus on the
double bond
and substituents
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What is the structural formula for hex-3-ene?
C6H10
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What does the term "highest priority group" refer to in stereochemistry?
The group with the largest
atomic mass
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How can you differentiate between E and Z isomers when drawing structures?
By checking the position of
highest priority groups
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What is the feature of the double bond that causes stereoisomerism?
Restricted rotation
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What is the importance of knowing the E/Z nomenclature in organic chemistry?
It helps in identifying
stereoisomers
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How do you determine the E or Z configuration for 3-methylpent-2-ene?
By analyzing the substituents across the
double bond
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