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CHEMISTRY
ORGANIC I
ALCOHOLS
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Cards (195)
What is the functional group in alcohols?
The O group
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What is an example of an alcohol mentioned in the video?
Ethanol
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What are the two methods to make ethanol mentioned?
Fermentation
and
hydration
of
ethene
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What is fermentation in the context of making ethanol?
Turning sugar into alcohol using
yeast
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What is the balanced equation for fermentation of glucose to ethanol?
C
6
H
12
O
6
→
2
C
2
H
5
O
H
+
C_6H_{12}O_6 \rightarrow 2C_2H_5OH +
C
6
H
12
O
6
→
2
C
2
H
5
O
H
+
2
C
O
2
2CO_2
2
C
O
2
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What is a key requirement for fermentation to occur?
It needs an
oxygen-free
environment
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What temperature range is optimal for yeast during fermentation?
30 to 40°C
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What is a disadvantage of the fermentation process?
It is a
batch process
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Why is ethanol considered a renewable resource in fermentation?
Because
sugar
used is renewable
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What is a disadvantage of ethanol produced by fermentation?
Ethanol needs
distilling
for purity
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What is the equation for hydration of ethene to produce ethanol?
C
2
H
4
+
C_2H_4 +
C
2
H
4
+
H
2
O
→
C
2
H
5
O
H
H_2O \rightarrow C_2H_5OH
H
2
O
→
C
2
H
5
O
H
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What catalyst is used in the hydration of ethene?
Phosphoric acid
or
sulfuric acid
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What are the conditions required for the hydration of ethene?
300°C
and
70 atmospheres
pressure
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What is an advantage of the hydration process compared to fermentation?
It is a
continuous process
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Why is ethanol produced from ethene considered non-renewable?
It comes from
crude oil
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What is a key characteristic of ethanol as a biofuel?
It is considered
carbon neutral
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Why is ethanol considered carbon neutral?
No net release of
CO2
in processes
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What is a limitation of the carbon neutrality claim for ethanol?
Transport and machinery produce
CO2
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What is the equation for photosynthesis?
6
C
O
2
+
6CO_2 +
6
C
O
2
+
6
H
2
O
→
C
6
H
12
O
6
+
6H_2O \rightarrow C_6H_{12}O_6 +
6
H
2
O
→
C
6
H
12
O
6
+
6
O
2
6O_2
6
O
2
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What happens to CO2 during the ethanol production cycle?
It is absorbed during
photosynthesis
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How does the ethanol production cycle demonstrate carbon neutrality?
CO2
absorbed equals CO2
released
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What is a common misconception about ethanol's carbon neutrality?
It ignores
transport
and
machinery
CO2
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Why is the claim of carbon neutrality by the company misleading?
Transport and machinery emissions are not considered
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What is produced during fermentation of planting material?
Ethanol
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What is the main argument against the carbon neutrality of biofuels?
Production processes emit CO2
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What are the classifications of alcohols?
Primary
Secondary
Tertiary
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How can you identify a primary alcohol?
It has one alkyl group attached to the carbon
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What is the displayed formula for ethanol?
C
H
3
C
H
2
O
H
CH_3CH_2OH
C
H
3
C
H
2
O
H
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What determines the classification of an alcohol?
The number of
alkyl groups
attached to the
carbon
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How does the oxidation of primary alcohols differ from tertiary alcohols?
Primary alcohols can be oxidized,
tertiary cannot
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What are the oxidation products of primary alcohols?
Aldehydes
and carboxylic acids
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What is the oxidation product of secondary alcohols?
Ketones
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What is the oxidizing agent used for alcohol oxidation?
Potassium dichromate
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What color change indicates oxidation with potassium dichromate?
Orange
to
green
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How can you produce ethanal from ethanol?
Oxidize
ethanol and distill
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What happens during the oxidation of ethanol to ethanal?
Two
hydrogens
are removed, producing
water
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What is the functional group of aldehydes?
C
H
O
CHO
C
H
O
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What is the final product when ethanal is oxidized?
Ethanoic acid
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What method is used to ensure complete oxidation to carboxylic acid?
Heating under reflux
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What is the purpose of distillation in the oxidation of ethanol?
To prevent further oxidation to
acid
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