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Chemistry A2 unit 4
organic reactions
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Cards (4)
ester with nitrile, with acid
RCN + HCl +
2H2O
--> RCOOH +
NH4Cl
aqueous
HCl (water)
heat under reflux
ester with nitrile, with alkali
RCN +NaOH + H2O --> RCOONa + NH3
aqueous NaOH
heat under reflux
acid catalysed hydrolysis of ester
RCOOR + H2O </> RCOOH + ROH
reversible, lower yield
dilute HCl (water)
base catalysed
hydrolysis of
ester
RCOOR +
NaOH
--> RCOONa + ROH
not
reversible
, higher yield
sodium hydroxide solution (water)