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chemistry
bonding and structure
intermolecular forces 2
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Cards (21)
What are induced dipole-dipole interactions also known as?
London dispersion forces
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How are induced dipole-dipole interactions formed?
From
temporary dipoles
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What causes the formation of temporary dipoles?
The constant motion of
electron clouds
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What happens to electron density in a temporary dipole?
It can shift to different sides of the
molecule
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What are the characteristics of temporary dipoles?
They have
partial charges
that change rapidly
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How does a temporary dipole affect nearby molecules?
It
induces
dipoles in nearby molecules
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What is an induced dipole interaction?
Attraction
between an
induced dipole
and an
initial dipole
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What factors affect the strength of London dispersion forces?
The number of
electrons
in a molecule
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Why do molecules with many electrons have stronger London dispersion forces?
They have larger
fluctuations
in electron density
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What are permanent dipole-dipole interactions?
Interactions between two permanently
polar molecules
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What defines a permanent dipole?
A molecule with a
δ-
on one side and a
δ+
on the other
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How do permanent dipoles interact with each other?
The
δ+
of one attracts the
δ-
of another
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What type of molecules can exhibit permanent dipole-dipole interactions?
Polar molecules
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What are hydrogen bonds?
Strong
permanent dipole-permanent dipole forces
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When do hydrogen bonds occur?
When hydrogen is bonded to
electronegative
elements
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Which elements can form hydrogen bonds with hydrogen?
Oxygen
,
nitrogen
, or fluorine
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Why does hydrogen form strong bonds with electronegative elements?
It develops a strong
δ+
charge
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What is the significance of hydrogen's small size in bonding?
It leads to high
charge density
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What are the types of intermolecular forces discussed?
Induced dipole-dipole interactions (
London dispersion forces
)
Permanent dipole-dipole interactions
Hydrogen bonds
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What are the strengths of different intermolecular forces?
London dispersion forces
: weakest
Permanent dipole-dipole interactions
: second strongest
Hydrogen bonds
: strongest
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What are the characteristics of polar molecules?
Have
permanent dipoles
Exhibit permanent
dipole-dipole interactions
Can form
hydrogen bonds
with specific elements
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