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Organic chemistry
Organic mechanism
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Bakhtawar rai
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Cards (74)
What type of substitution is discussed first in the video?
Nucleophilic substitution
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What are the two common halogens mentioned for nucleophilic substitution?
Bromine
and
chlorine
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What does a nucleophile do in nucleophilic substitution?
Attacks the
positively charged
carbon
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What is a curly arrow used to represent?
Movement of a
pair of electrons
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What does a two-headed curly arrow indicate?
Movement of a
pair of electrons
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What happens when a nucleophile donates a lone pair?
Forms a
dative covalent bond
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In the example with hydroxide, what does the hydroxide ion attack?
A hydrogen atom on the
haloalkane
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What is formed when the hydroxide ion attacks the carbon?
An
alcohol
and a
bromide
ion
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What is the product when cyanide ion is used as a nucleophile?
A
nitrile
compound
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What happens to ammonia when it acts as a nucleophile?
It forms a
positive charge
after bonding
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How does a primary amine react in subsequent nucleophilic substitution?
It can act as a
nucleophile
itself
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What is the product of a secondary amine reacting with a haloalkane?
A
tertiary amine
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What is a quaternary ammonium salt?
A
nitrogen
with four
carbon
chains
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What is the result of elimination reactions with hydroxide ions?
Formation of an
alkene
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What does the hydroxide ion attack in elimination reactions?
A hydrogen atom on the
haloalkane
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What is the mechanism for alkenes discussed in the video?
Electrophilic addition
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What is an electrophile?
An
electron pair
acceptor
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What is the electron density in an alkene due to?
The presence of
double bonds
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What are the electrophiles mentioned for electrophilic addition?
Diatomic
halogens,
hydrogen halides
, sulfuric acid
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What is the dipole present in diatomic halogens?
Delta
positive
and
delta
negative
charges
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How does electronegativity affect dipoles in molecules?
It creates regions of
partial
positive and negative charge
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What is a leaving group in nucleophilic substitution?
A group that departs with an
electron pair
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Why is it important to show dipoles in mechanisms?
To indicate
electron density
and
charge distribution
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What role do lone pairs play in nucleophilic attacks?
They provide
electrons
for bond formation
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What are the diatomic halogens you need to know?
Cl<sub>2</sub>
,
Br<sub>2</sub>
, etc.
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What is an example of a hydrogen halide?
Hydrogen bromide
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What is the chemical formula for sulfuric acid?
H<sub>2</sub>SO<sub>4</sub>
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What is the process of electrophilic addition with diatomic halogens?
Diatomic halogen (e.g., Br<sub>2</sub>) induces a dipole.
Electrons from double bond attract to positive halogen.
One halogen atom bonds, the other leaves as a
halide ion
.
Forms a
carbocation
intermediate.
Final product is a dibromo compound.
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How does a dipole form in diatomic bromine?
Identical atoms create a
temporary
dipole.
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What happens to the double bond during electrophilic addition with bromine?
The
double bond
breaks
to form a
single bond.
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What type of ion is formed when bromine leaves in electrophilic addition?
Bromide ion
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What is a carbocation?
A
positively
charged
carbon
ion.
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What are the types of carbocations?
Primary
,
secondary
,
tertiary
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What is the product of the reaction between an alkene and hydrogen bromide?
Bromoalkane
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What is the process of electrophilic addition with hydrogen halides?
Hydrogen halide (e.g., HBr) has a
dipole
.
Electrons from double bond attract to positive hydrogen.
Bromine leaves as a bromide ion.
Forms a
carbocation
intermediate.
Final product is a haloalkane.
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How does sulfuric acid behave in electrophilic addition?
Acts similarly to
hydrogen halides
.
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What is the product of the reaction with sulfuric acid?
Alkyl hydrogen sulfate
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What is the hydration of ethene process?
H<sup>+</sup> from
phosphoric acid
attacks ethene.
Forms a
carbocation
intermediate.
Water donates a
lone pair
to form an
alcohol
.
Final product is an alcohol.
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What is the strong acid used in the hydration of ethene?
Phosphoric acid
(
H<sub>3</sub>PO<sub>4</sub>
)
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What is the acid-catalyzed elimination reaction?
Alcohol reacts with a strong acid.
Forms a
carbocation
intermediate.
Water is eliminated, forming an
alkene
.
Final product is an alkene.
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