Organic mechanism

Cards (74)

  • What type of substitution is discussed first in the video?
    Nucleophilic substitution
  • What are the two common halogens mentioned for nucleophilic substitution?
    Bromine and chlorine
  • What does a nucleophile do in nucleophilic substitution?
    Attacks the positively charged carbon
  • What is a curly arrow used to represent?
    Movement of a pair of electrons
  • What does a two-headed curly arrow indicate?
    Movement of a pair of electrons
  • What happens when a nucleophile donates a lone pair?
    Forms a dative covalent bond
  • In the example with hydroxide, what does the hydroxide ion attack?
    A hydrogen atom on the haloalkane
  • What is formed when the hydroxide ion attacks the carbon?
    An alcohol and a bromide ion
  • What is the product when cyanide ion is used as a nucleophile?
    A nitrile compound
  • What happens to ammonia when it acts as a nucleophile?
    It forms a positive charge after bonding
  • How does a primary amine react in subsequent nucleophilic substitution?
    It can act as a nucleophile itself
  • What is the product of a secondary amine reacting with a haloalkane?
    A tertiary amine
  • What is a quaternary ammonium salt?
    A nitrogen with four carbon chains
  • What is the result of elimination reactions with hydroxide ions?
    Formation of an alkene
  • What does the hydroxide ion attack in elimination reactions?
    A hydrogen atom on the haloalkane
  • What is the mechanism for alkenes discussed in the video?
    Electrophilic addition
  • What is an electrophile?
    An electron pair acceptor
  • What is the electron density in an alkene due to?
    The presence of double bonds
  • What are the electrophiles mentioned for electrophilic addition?
    Diatomic halogens, hydrogen halides, sulfuric acid
  • What is the dipole present in diatomic halogens?
    Delta positive and delta negative charges
  • How does electronegativity affect dipoles in molecules?
    It creates regions of partial positive and negative charge
  • What is a leaving group in nucleophilic substitution?
    A group that departs with an electron pair
  • Why is it important to show dipoles in mechanisms?
    To indicate electron density and charge distribution
  • What role do lone pairs play in nucleophilic attacks?
    They provide electrons for bond formation
  • What are the diatomic halogens you need to know?
    Cl<sub>2</sub>, Br<sub>2</sub>, etc.
  • What is an example of a hydrogen halide?
    Hydrogen bromide
  • What is the chemical formula for sulfuric acid?
    H<sub>2</sub>SO<sub>4</sub>
  • What is the process of electrophilic addition with diatomic halogens?
    • Diatomic halogen (e.g., Br<sub>2</sub>) induces a dipole.
    • Electrons from double bond attract to positive halogen.
    • One halogen atom bonds, the other leaves as a halide ion.
    • Forms a carbocation intermediate.
    • Final product is a dibromo compound.
  • How does a dipole form in diatomic bromine?
    Identical atoms create a temporary dipole.
  • What happens to the double bond during electrophilic addition with bromine?
    The double bond breaks to form a single bond.
  • What type of ion is formed when bromine leaves in electrophilic addition?
    Bromide ion
  • What is a carbocation?
    A positively charged carbon ion.
  • What are the types of carbocations?
    Primary, secondary, tertiary
  • What is the product of the reaction between an alkene and hydrogen bromide?
    Bromoalkane
  • What is the process of electrophilic addition with hydrogen halides?
    • Hydrogen halide (e.g., HBr) has a dipole.
    • Electrons from double bond attract to positive hydrogen.
    • Bromine leaves as a bromide ion.
    • Forms a carbocation intermediate.
    • Final product is a haloalkane.
  • How does sulfuric acid behave in electrophilic addition?
    Acts similarly to hydrogen halides.
  • What is the product of the reaction with sulfuric acid?
    Alkyl hydrogen sulfate
  • What is the hydration of ethene process?
    • H<sup>+</sup> from phosphoric acid attacks ethene.
    • Forms a carbocation intermediate.
    • Water donates a lone pair to form an alcohol.
    • Final product is an alcohol.
  • What is the strong acid used in the hydration of ethene?
    Phosphoric acid (H<sub>3</sub>PO<sub>4</sub>)
  • What is the acid-catalyzed elimination reaction?
    • Alcohol reacts with a strong acid.
    • Forms a carbocation intermediate.
    • Water is eliminated, forming an alkene.
    • Final product is an alkene.