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CHM02
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Cards (32)
Energy
capacity
to do work and release heat
known and
characterized
by its effects
cannot be seen, touched, smelled, or weighed
Kinetic Energy
associated with
movements
mechanical
thermal
electrical
acoustic
Potential Energy
results from an object's position or state
chemical
gravitational
elastic
electrostatic
1 calorie
heat required to raise the temperature of 1 g of water by
1 C
1000
cal =
1 kilocalorie
1 kcal
=
1 Calorie
(food calorie)
1 cal =
4.184 J
Heat
transferred from a body
high
temperature
to lower temperature
Heat Flow
transfer
of heat
Thermochemistry
study of heat change in
chemical
reactions
System
part of the
universe
on which is attention is focused
Open System
can lose or gain
mass
and
energy
to across the surroundings
Closed System
can absorb or release
energy
but not mass across the surroundings
Isolated System
cannot exchange matter or energy with their surroundings
adiabatic system
Surroundings
part of the
universe
that exchange energy with the
system
.
rest of the universe
in close contact with the system
State of the System
composition
(g)
temperature
pressure
Endothermic Process
heat flows from the surroundings into the system
system absorbs
energy increases into the system
energy decreases in the surroundings
internal
Exothermic Process
heat from the
system
to the
surroundings
system releases
energy
decreases in the system
energy increases in the surrounding
external
Thermodynamics
scientific study of the interconversion of
heat
and other kinds of energy
Zeroth Law
If two thermodynamic systems are each in
thermal equilibrium
with a third, then they are in thermal equilibrium with each other
First Law
law of
conservation of energy
Energy can neither be
created
nor
destroyed
; energy can only be transformed
Internal Energy
contained within a system
composed of
kinetic
and
potential
energy
Work done by the system
negative
Work done on the system
Positive
Heat absorbed by the system
endothermic process
positive
Heat released by the system
exothermic process
negative
Specific Heat
one
gram
of the substance
Heat Capacity
given
quantity
of a substance
Constant Volume Calorimetry
combustion reaction
bomb calorimeter
Constant Pressure Calorimetry
non-combustion reaction
coffee cup calorimeter
Spontaneous Reaction
favors the
formation
of products
ice cube that melts at
room temperature
Non Spontaneous Energy
does not favor the
formation
of products
photosynthesis
More microstate
Higher
entropy
Fewer microstate
lower
entropy
Gibbs
Free
Energy
available energy of a substance that can be used in a chemical equation