aldehydes and ketones

Cards (46)

  • What is the carbonyl functional group represented as?
    C double bond O
  • Where is the carbonyl group located in aldehydes?
    At the end of the carbon chain
  • How do aldehydes typically end in nomenclature?
    They end in -al
  • What is an example of an aldehyde mentioned in the video?
    Propanal
  • How do ketones typically end in nomenclature?
    They end in -one
  • Where is the carbonyl group located in ketones?
    In the middle of the carbon chain
  • What is an example of a ketone mentioned in the video?
    Propanone
  • What happens to aldehydes when they are oxidized?
    They form carboxylic acids
  • Can ketones be oxidized?
    No, ketones cannot be oxidized
  • What reagent is used to distinguish between aldehydes and ketones?
    Tollens' reagent
  • What is the result of the silver mirror test with aldehydes?
    A silver mirror forms
  • What is the first step in making Tollens' reagent?
    Add silver nitrate to a test tube
  • What color does Fehling's solution turn if an aldehyde is present?
    From blue to brick red
  • What do both Tollens' reagent and Fehling's solution have in common?
    They are both oxidizing agents
  • What do aldehydes reduce to?
    Primary alcohols
  • What do ketones reduce to?
    Secondary alcohols
  • What reducing agent is mentioned for reducing aldehydes and ketones?
    Sodium borohydride
  • How is a reducing agent represented in chemical equations?
    With H in square brackets
  • What is the role of hydrogen in the reduction of aldehydes and ketones?
    It acts as the reducing agent
  • How many reducing agents are needed to reduce an aldehyde to a primary alcohol?
    Two reducing agents
  • What is the product of reducing a ketone?
    A secondary alcohol
  • What is the general outcome of reducing both aldehydes and ketones?
    Both produce alcohols
  • What is required at the end of the oxygens in the molecule discussed?
    A hydrogen atom
  • Why do we need two of the mentioned molecules?
    To balance the hydrogen atoms
  • What type of alcohol do ketones primarily form when reduced?
    Secondary alcohols
  • What is the reducing agent mentioned for ketones?
    Sodium borohydride (NaBH4)
  • What do all aldehydes produce when reduced?
    Primary alcohols
  • What is the role of the hydride ion (H-) in the reduction of aldehydes and ketones?
    It acts as a reducing agent
  • How does the mechanism for reducing aldehydes differ from ketones?
    There is no difference in the mechanism
  • What happens to the electrons in the double bond during the reduction mechanism?
    They break and move to the oxygen
  • What type of reaction occurs when aldehydes or ketones react with potassium cyanide?
    Nucleophilic addition reaction
  • What is formed when a hydroxy nitrile is produced?
    It contains both hydroxyl and nitrile groups
  • What is the generic equation for the reaction of an aldehyde with potassium cyanide?
    Aldehyde + KCN + H+ → Hydroxy nitrile
  • What happens when using unsymmetrical ketones or aldehydes in reactions?
    A mixture of enantiomers is produced
  • Why is potassium cyanide preferred over hydrogen cyanide in reactions?
    It is easier to handle and less toxic
  • What precautions should be taken when handling potassium cyanide?
    Wear gloves and safety goggles
  • What can potassium cyanide produce when it reacts with moisture?
    Toxic hydrogen cyanide gas
  • What should be done to prevent skin contact with potassium cyanide?
    Wear gloves during handling
  • Why is it important to wear safety goggles in the lab?
    To protect eyes from harmful substances
  • What is the purpose of wearing a lab coat in the lab?
    To prevent clothing contamination