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Organic chemistry
aldehydes and ketones
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Cards (46)
What is the carbonyl functional group represented as?
C double bond O
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Where is the carbonyl group located in aldehydes?
At the end of the
carbon chain
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How do aldehydes typically end in nomenclature?
They end in
-al
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What is an example of an aldehyde mentioned in the video?
Propanal
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How do ketones typically end in nomenclature?
They end in
-one
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Where is the carbonyl group located in ketones?
In the middle of the
carbon chain
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What is an example of a ketone mentioned in the video?
Propanone
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What happens to aldehydes when they are oxidized?
They form
carboxylic acids
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Can ketones be oxidized?
No,
ketones cannot
be
oxidized
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What reagent is used to distinguish between aldehydes and ketones?
Tollens'
reagent
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What is the result of the silver mirror test with aldehydes?
A
silver mirror forms
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What is the first step in making Tollens' reagent?
Add
silver nitrate
to a test tube
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What color does Fehling's solution turn if an aldehyde is present?
From
blue
to
brick red
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What do both Tollens' reagent and Fehling's solution have in common?
They are both
oxidizing
agents
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What do aldehydes reduce to?
Primary alcohols
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What do ketones reduce to?
Secondary alcohols
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What reducing agent is mentioned for reducing aldehydes and ketones?
Sodium borohydride
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How is a reducing agent represented in chemical equations?
With
H in
square brackets
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What is the role of hydrogen in the reduction of aldehydes and ketones?
It acts as the
reducing agent
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How many reducing agents are needed to reduce an aldehyde to a primary alcohol?
Two
reducing agents
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What is the product of reducing a ketone?
A
secondary alcohol
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What is the general outcome of reducing both aldehydes and ketones?
Both produce
alcohols
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What is required at the end of the oxygens in the molecule discussed?
A
hydrogen atom
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Why do we need two of the mentioned molecules?
To balance the
hydrogen atoms
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What type of alcohol do ketones primarily form when reduced?
Secondary alcohols
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What is the reducing agent mentioned for ketones?
Sodium borohydride
(
NaBH4
)
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What do all aldehydes produce when reduced?
Primary alcohols
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What is the role of the hydride ion (H-) in the reduction of aldehydes and ketones?
It acts as a
reducing agent
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How does the mechanism for reducing aldehydes differ from ketones?
There
is
no
difference
in
the
mechanism
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What happens to the electrons in the double bond during the reduction mechanism?
They break and move to the
oxygen
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What type of reaction occurs when aldehydes or ketones react with potassium cyanide?
Nucleophilic addition reaction
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What is formed when a hydroxy nitrile is produced?
It contains both
hydroxyl
and nitrile groups
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What is the generic equation for the reaction of an aldehyde with potassium cyanide?
Aldehyde + KCN + H+ →
Hydroxy nitrile
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What happens when using unsymmetrical ketones or aldehydes in reactions?
A
mixture
of
enantiomers
is produced
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Why is potassium cyanide preferred over hydrogen cyanide in reactions?
It is easier to handle and less
toxic
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What precautions should be taken when handling potassium cyanide?
Wear
gloves
and
safety goggles
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What can potassium cyanide produce when it reacts with moisture?
Toxic
hydrogen cyanide
gas
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What should be done to prevent skin contact with potassium cyanide?
Wear
gloves
during handling
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Why is it important to wear safety goggles in the lab?
To protect eyes from
harmful substances
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What is the purpose of wearing a lab coat in the lab?
To prevent
clothing contamination
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