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Organic chemistry
carboxylic acids and derivatives
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Cards (116)
What type of acids are carboxylic acids?
Weak acids
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What do carboxylic acids produce when they react with carbonates?
Carbon dioxide
,
salt
, and water
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What does the equilibrium of weak acids favor?
The carboxylic acid form
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What is the reaction of ethanoic acid with sodium carbonate?
Produces sodium
ethanoate
, water, and
CO<sub>2</sub>
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What is the role of sulfuric acid in esterification?
It acts as a
catalyst
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What is formed when a carboxylic acid reacts with an alcohol?
An
ester
and
water
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What is an acid anhydride?
A
carboxylic acid
without the
hydroxyl group
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How are esters named?
From the
alcohol
and
carboxylic acid
used
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What is the first part of an ester name derived from?
The
alcohol
used in the reaction
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How do you name an ester formed from ethanol and propanoic acid?
Ethyl propanoate
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What is a common use of esters in the industry?
In
perfumes
and food flavorings
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What is a characteristic smell of esters?
Sweet smell
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Why are esters used in glues?
They
evaporate
easily, leaving a solid
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What is the role of plasticizers in plastics?
To make
plastics
more
flexible
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What is a concern regarding plasticizers in children's toys?
They can
leach
out and be
toxic
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What is the purpose of glue when applied to a surface?
To
harden
and stick objects together
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What happens to glue over time after application?
The
solvent
evaporates
, leaving hardened
resin
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How are plasticizers used in plastics?
To make plastics more flexible during
polymerization
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What is a common example of a product containing plasticizers?
Rubber
ducks
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Why are there strict laws regarding plasticizers in children's toys?
They can
leach
out and be
toxic
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What happens to plastics over time when exposed to sunlight?
They become
brittle
and break down
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What is hydrolysis in the context of esters?
Breaking down an ester using
water
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What are the two types of hydrolysis for esters?
Acid
hydrolysis and
base
hydrolysis
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What is the role of an acid in acid hydrolysis of esters?
To speed up the
reaction
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What is produced from acid hydrolysis of an ester?
A
carboxylic acid
and an alcohol
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What is the function of reflux in ester hydrolysis?
To prevent evaporation of
reactants
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What is the formula for glycerol?
C3H8O3
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What are the two types of fatty acids?
Saturated
and
unsaturated
fatty acids
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Why are saturated fats considered unhealthy?
They can increase
bad cholesterol
levels
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Where are unsaturated fats commonly found?
Nuts and
vegetable
oils
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What does the term "saturated" refer to in saturated fatty acids?
Maximum
hydrogen
atoms per
carbon
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What is produced when glycerol reacts with fatty acids?
An
ester
that makes fats and oils
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What is the difference between fats and oils in terms of structure?
Fats have
saturated
chains; oils have
unsaturated
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Why do oils have lower melting points than fats?
They cannot pack closely due to
double bonds
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What is the process of making soap from fats and oils?
Hydrolysis
with
sodium hydroxide
produces soap
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What is the role of sodium hydroxide in soap production?
It
hydrolyzes
fats and oils
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What type of ester is produced from animal fats?
A
saturated
ester
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How does the structure of saturated fats affect their physical state?
They pack tightly and are solid at
room temperature
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How can you differentiate between fats and oils based on their molecular structure?
Fats have no
double bonds
; oils have double bonds
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What is the significance of Van der Waals forces in fats and oils?
They determine
melting
and
boiling
points
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