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Physical Chemistry
Bonding
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Cards (57)
What type of elements participate in ionic bonding?
Metal and
non-metal
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What happens to electrons during ionic bonding?
Electrons are transferred from
metal
to
non-metal
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What are charged particles created during ionic bonding called?
ions
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What type of structure is formed by oppositely charged ions?
A giant
ionic lattice
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What ions are formed in sodium chloride?
Na
+ and
Cl
- ions
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How does sodium chloride achieve full outer electron shells?
Sodium
loses
an electron, chlorine
gains
one
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What are common compound ions?
Sulfate
-
SO42
-
Hydroxide
-
OH
-
Nitrate
-
NO3
-
Carbonate
-
CO32
-
Ammonium
-
NH4
+
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What type of elements form covalent bonds?
Two
non-metals
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How are electrons handled in covalent bonding?
Electrons are shared between
outer shells
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What can multiple electron pairs produce in covalent bonding?
Multiple covalent bonds
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How can shared electron pairs be represented?
Using
dot and cross diagrams
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What is a dative bond?
Electrons in the
shared pair
come from one atom
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What is an example of dative bonding?
Ammonia
forming
ammonium ion
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How is a dative bond treated after formation?
As a standard
covalent bond
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What is metallic bonding characterized by?
A lattice of
positively charged
ions
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What surrounds the positively charged ions in metallic bonding?
A ‘sea’ of
delocalised electrons
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What happens to the attractive force in metallic bonding as the charge increases?
The
attractive
force
becomes
stronger
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How does the size of ions affect metallic bonding?
Larger ions produce weaker
attraction
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What are physical properties of substances influenced by?
Type of bonding
and crystal structure
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What are the four main types of crystal structure?
Ionic
Metallic
Simple molecular
Macromolecular
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What is a characteristic of ionic substances regarding melting and boiling points?
They have
high
melting and boiling points
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Why do ionic substances conduct electricity when molten or in solution?
Ions
are free to move and carry
charge
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What happens to ionic substances when layers are distorted?
They break apart into
fragments
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What is a characteristic of metallic substances regarding conductivity?
They are good
conductors
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Why are metals malleable?
Layers of
positive ions
can slide over each other
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What is the state of most metallic substances at room temperature?
They are nearly always solid
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What type of structure do simple molecular substances have?
Covalently bonded
molecules
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What holds simple molecular substances together?
Weak
van der Waals forces
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Why do simple molecular substances have low melting and boiling points?
Weak forces
require little energy to overcome
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What is an example of a simple molecular substance with high boiling point?
Water
due to
hydrogen bonding
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What is a characteristic of macromolecular substances?
They have a
giant lattice structure
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What gives macromolecular substances a very high melting point?
Multiple strong
covalent bonds
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What makes diamond one of the hardest materials?
Its strong
covalent
lattice
structure
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How does graphite differ from diamond in structure?
Graphite has flat sheets of
carbon
atoms
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What allows graphite to conduct electricity?
Free electrons
move between layers
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What determines the shape of a molecule?
Number of
electron pairs
around
central atom
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How do electron pairs affect bond angles?
They
repel
each other to maximize angles
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What effect do lone pairs have on bond angles?
They reduce bond angles by
2.5°
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How do you determine the shape of a molecule?
Find the number of
electron pairs
.
Identify
bonding
and
lone pairs
.
Analyze the basic shape and
repulsion
effects.
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What are common molecule shapes and their bond angles?
Linear
:
180°
(2
bonding pairs
)
V-Shaped: 104.5° (2 bonding, 2
lone pairs
)
Trigonal Planar
: 120° (3 bonding pairs)
Triangular Pyramid
: 107° (3 bonding, 1 lone pair)
Tetrahedral:
109.5°
(4 bonding pairs)
Trigonal Bipyramid
: 90° and 120° (5 bonding pairs)
Octahedral
: 90° (6 bonding pairs)
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