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Chemistry
Module 3 - Periodic Table and Energy
Enthalpy
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enthalpy
is a measure of all heat energy in a chemical system
enthalpy change
Δ
H
\Delta H
Δ
H
= H(
products
) - H(
rectants
)
exothermic
change
energy from
system
to
surroundings
endothermic
change
energy from
surroundings
to system
exothermic
- energy out of the system
any energy loss from chemical system is balanced by same energy gain from the surroundings.
Δ
\Delta
Δ
H is
negative
temperature of surroundings
increases
as they gain energy
endothermic
- heat into the system
chemical system that takes
in
heat energy from the
surroundings
any energy gain is balanced by the same energy loss to the surroundings
∆H is
positive
temperature of surroundings
decrease
as they lose energy
enthalpy change of
formation
enthalpy change that takes place when one
mole
of a compound is
formed
from its elements under standard conditions
standard enthalpy change of
combustion
enthalpy
change that takes place when one mole of a substance reacts completely with
oxygen
under standard conditions
when a substance reacts completely with
oxygen
the products are
oxides
of the elements in the substance
standard enthalpy change of neutralisation
energy change that accompanies the reaction of an
acid
by a
base
to form
one mole of H2O
under standard conditions
for
enthalpy
change of neutralisation the reaction involves
H+
with
OH-
to form one mole of H2O
specific heat capacity
energy required to raise the temperature of
1g
of a substance by
1 K
average bond enthalpy
energy required to break
one mole
of a
specified
type of bond in a
gaseous
molecule
bond
enthalpies
are always endothermic so always have a
positive
enthalpy value
bond
breaking
endothermic
as energy is
required
bond
making
exothermic
because energy is
released