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CHEMISTRY
Amines
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Amine
is derived from
ammonia
molecules and all contain a
nitrogen
atom,
hydrogen
replaced with organic group.
Quaternary
ion
-
4
organic groups
Non aromatic
amines are known as
aliphatic amines
.
Quaternary ammonium salts
are used to make cleaning products. Quaternary ammonium salts with tails are called
cationic surfactants
.
Non polar
tails attracted to
oil
and
greese
. Polar head attracted to water. Allows water and oil to mix.
Cationic
surfactants a have positive
ammonium
ion that are attracted to negative fibres in the hair, removes
static
and used in conditioner.
Benzene
is an
electron withdrawing group
.
Alkyl groups
are
electron pushing groups
Reducing
Nitriles
LiAlH4
, reducing
Nitriles
Making
Aromatic Amines
Positive Inductive effect
=
R groups
push electrons
Availability of
LP
, L.P
gain H+
, More R greater
electron releasing group
,
electron density
increases.
Hydrogenation
= adding on hydrogen
volatile
substance = use
reflux
, means tendency to vaporise, if done in
beaker
product and reactant will be lost
Chain reaction
keeps reaction so we cannot obtain 100%
yield
.