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Physical chem
1.8 thermodynamics
5. Entropy
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Cards (13)
Define
entropy
Measurement of
disorder
How do we represent entropy ?
S
The more
disorder
there is the ….. the
level
of entropy
Higher
As states change from solid to gas, does
entropy
increase?
yes
Why is entropy lowest at solids ?
Particles
vibrate in arranged neat rows
What can be determined from this graph abound entropy while changing
states
?
Gas>liquid> solid
Entropy
increase by
temperature
Big increase when changing states (
melting/boiling
)
Entropy change for liquid to gas is greater than
solid to liquid
Why is the entropy larger as you change states?
The higher the
temperature
, the faster the
particles
vibrate and move so greater the entropy(disorder)
How does entropy between different sized molecules compare ?
Increase in molecule size = more entropy as more
bonds
and more
atoms
so more disorder resulting in an increase in entropy
How does entropy compare with different ionic bonding?
Depends on
strength
of ionic bonding
The stronger the ionic bonds = lower the entropy
The weaker the ionic bonds = the stronger the entropy
How does entropy compare when compound is dissolved in a solvent?
Increase as there is an increase in
randomness
What is larger enthalpy or entropy ?
Enthalpy is larger as it is
measured
in
KJ
and entropy is measured in J
What is the units for entropy (S)?
JK-1mol-1
What is the equation for finding entropy ?
Sum of products - sum of
reactants