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chemistry
electrolysis of aluminium oxide
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Cards (22)
What is the purpose of electrolysis in metal extraction?
To extract some
metals
from compounds
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Why is aluminium extracted using electrolysis?
Because it is more reactive than carbon
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What is the compound used to extract aluminium?
Aluminium oxide
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What is the melting point of aluminium oxide?
Approximately
2000°
C
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What compound is mixed with aluminium oxide to lower its melting point?
Cryolite
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Why is cryolite added to aluminium oxide?
To reduce energy needed for
melting
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What materials are the electrodes made of in the electrolysis setup?
Graphite
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Why is graphite used for electrodes in electrolysis?
It conducts
electricity
and has a high
melting point
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What ions are present in molten aluminium oxide?
Aluminium
ions
A
l
3
+
Al^{3+}
A
l
3
+
and oxide ions
O
2
−
O^{2-}
O
2
−
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What happens to aluminium ions at the cathode?
They gain
electrons
to form
aluminium atoms
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What is the half equation for the reaction at the cathode?
A
l
3
+
+
Al^{3+} +
A
l
3
+
+
3
e
−
→
A
l
3e^{-} \rightarrow Al
3
e
−
→
A
l
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What happens to oxide ions at the anode?
They lose
electrons
to form
oxygen atoms
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What is the half equation for the reaction at the anode?
O
2
−
→
1
2
O
2
+
O^{2-} \rightarrow \frac{1}{2}O_{2} +
O
2
−
→
2
1
O
2
+
2
e
−
2e^{-}
2
e
−
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What do the oxygen atoms formed at the anode do?
They pair up to form oxygen molecules
O
2
O_{2}
O
2
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Why must the anode be replaced regularly?
It reacts with oxygen to form
carbon dioxide
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What gas is produced when oxygen reacts with graphite at the anode?
Carbon dioxide
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Why is electrolysis expensive for metal production?
It requires a lot of energy for
melting
and electricity
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What are the two main energy costs in electrolysis?
Melting the compound and producing
electric current
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What are the steps involved in the electrolysis of aluminium oxide?
Aluminium oxide is mixed with
cryolite
.
Electric current is applied to molten aluminium oxide.
Aluminium ions
A
l
3
+
Al^{3+}
A
l
3
+
move to the cathode and gain electrons.
Oxide ions
O
2
−
O^{2-}
O
2
−
move to the anode and lose electrons.
Oxygen atoms pair to form
O
2
O_{2}
O
2
molecules.
Anode must be replaced due to reaction with oxygen.
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What are the differences between reduction and oxidation in electrolysis?
Reduction: Gain of electrons (at
cathode
)
Oxidation: Loss of electrons (at
anode
)
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What are the properties of graphite that make it suitable for electrodes in electrolysis?
Good conductor of electricity
High melting point
Stable at high temperatures
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What are the implications of using electrolysis for metal extraction?
High
energy costs
Requires careful management of resources
Environmental considerations due to
gas emissions
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