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chemistry
physical
atomic structure
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Cards (48)
What has caused the model for atomic structure to evolve over time?
Changes
in knowledge and
scientific understanding
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What did the Plum Pudding Model propose about atomic structure?
Atoms consist of a sphere of
positive charge
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What is the current understanding of atomic structure?
Atoms have a dense
nucleus
with orbiting
electrons
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What experiment led to the discovery of the electron shell model?
The
Rutherford
scattering
experiment in
1911
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What particles make up the nucleus of an atom?
Protons
and
neutrons
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What charge does the nucleus of an atom have?
Overall
positive
charge
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What is the relationship between protons and electrons in a neutral atom?
They are equal in
number
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What is the relative charge of a proton?
+1
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What is the relative charge of a neutron?
0
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What is the relative charge of an electron?
-1
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What is the relative mass of a proton?
1
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What is the relative mass of a neutron?
1
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What is the relative mass of an electron?
1/1840
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How can the maximum number of orbiting electrons in a shell be calculated?
Using the
formula
2
n
2
2n^2
2
n
2
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How many electrons can shell 2 hold?
8
electrons
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What must happen before the next electron shell can hold electrons?
Each electron shell must
fill
first
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What does mass number represent?
The sum of
protons
and
neutrons
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What is atomic number represented by?
Z
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What does atomic number equal?
The number of
protons
in an atom
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If an atom has an atomic number of
7
and a mass number of
14
, how many
neutrons
does
it
have?

7 neutrons
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What is relative atomic mass defined as?
Mean mass of an atom divided by
carbon-12
mass
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What do isotopes have in common?
Same
atomic number
but different
neutrons
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How do neutral atoms of isotopes react chemically?
They react the same way
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What is the effect of different mass numbers on isotopes?
They have different physical properties
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What is an ion?
An atom that has lost or gained
electrons
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What is mass spectrometry used for?
To identify different
isotopes
and relative
atomic mass
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What does Time of Flight (TOF) Mass Spectrometry measure?
The time
ions
take to reach a detector
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What are the steps of the mass spectrometry process?
Ionisation
: Sample vapourised and ionised
Acceleration
: Ions accelerated towards
detection plate
Ion Drift: Ions deflected by magnetic field
Detection: Ions hit detection plate, producing charge
Analysis
: Current values used to produce spectra
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What happens during the ionisation process in mass spectrometry?
Electrons
are removed, creating +1
charged
ions
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What is the effect of a 2+ charged ion in mass spectrometry?
It has a
smaller
radius
path
in the magnetic field
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How is relative atomic mass (Ar) calculated using isotopes?
Using the
formula
A
r
=
Ar =
A
r
=
(
10
x
75
)
+
(10x75) +
(
10
x
75
)
+
(
12
x
25
)
/
(
75
+
25
)
(12x25) / (75 + 25)
(
12
x
25
)
/
(
75
+
25
)
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What does the chlorine spectra produced by mass spectrometry show?
A characteristic pattern in a
3:1 ratio
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What are the types of electron orbitals?
s, p, d, and f
orbitals
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How many electrons can an s-orbital hold?
2
electrons
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How many electrons can a p-orbital hold?
6
electrons
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How many electrons can a d-orbital hold?
10
electrons
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In what order are orbitals filled?
From
s to d
, increasing
energy
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What is the electron configuration of sodium (Na)?
Na =
1
s
2
2
s
2
2
p
6
3
s
1
1s^2 2s^2 2p^6 3s^1
1
s
2
2
s
2
2
p
6
3
s
1
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What is the significance of electron pairing in orbitals?
It stabilizes the
atom
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What are the three rules for writing electron configurations?
Fill
lowest energy
orbital first
Same spin fills
orbitals
first
No more than 2 electrons
per orbital
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