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chemistry
physical
equilibria
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Created by
james
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Cards (27)
What type of reactions are reversible?
Reactions where
products
can reform
reactants
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How is a reversible reaction represented?
Using a
double arrow
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What characterizes the two reactions in a reversible system?
One is
endothermic
, the other
exothermic
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What is dynamic equilibrium in reversible reactions?
Forward and backward
reaction rates
are equal
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What happens to concentrations at dynamic equilibrium?
Concentrations
of
reactants
and
products
are
constant
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In what type of system does dynamic equilibrium occur?
Closed systems
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What does Le Chatelier’s Principle predict?
How
equilibrium
will change with altered conditions
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What does Le Chatelier’s Principle state about a system under change?
The
system
will
alter
to
lessen
the
change's
effect
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How can Le Chatelier’s Principle be useful in industry?
To maximize the
yield
of desired products
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What effect does increasing temperature have on endothermic reactions?
It
favors
the
endothermic reaction
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What happens when temperature is decreased in a reaction?
It favors the
exothermic
reaction
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What is the sign of ∆H for endothermic reactions?
Positive
(+ve ∆H)
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What is the sign of ∆H for exothermic reactions?
Negative
(-ve ∆H)
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What effect does increasing pressure have on a reaction?
It favors the side with fewer
moles
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What happens when pressure is decreased in a reaction?
It favors the side with more
moles
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What effect does increasing the concentration of reactants have?
It favors the production of
products
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What happens when the concentration of products is decreased?
It favors the reforming of
reactants
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How do catalysts affect equilibrium position?
Catalysts
do
not
affect
equilibrium
position
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What do catalysts do to the rate of reaching equilibrium?
They allow equilibrium to be reached faster
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What does Kc represent in reversible reactions?
The
position
of
equilibrium
at
a
certain
temperature
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When does the value of Kc change?
When reaction
conditions
change
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How is Kc calculated?
Concentration
of products divided by reactants
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What happens to the number of moles in the Kc expression?
Each substance is raised to the
power
of its moles
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How do the units of Kc vary?
They depend on the
chemical reaction
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What does changing temperature do to Kc?
It
affects
the
value
of
Kc
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What does changing concentration do to Kc?
It
does
not
affect
the
value
of
Kc
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How does a catalyst affect Kc?
A
catalyst
does
not
affect the
value
of
Kc
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