Periodicity is the pattern in physical and chemical properties of elements in the periodic table.
S block elements are group 1, 2 and Helium.
N2, O2, F2, Ne, P4, S8, Cl2 and Ar form simple molecular structures held together by weak london forces.
B, C and Si form giant covalent structures with high melting points because of strong covalent bonds.
Metals form giant metallic structures with strong electrostatic forces between metal ions and delocalised electrons.
Across a Period, Number of protons increases so there is a larger nuclear pull but electron shielding remains constant so outer electrons become closer to the nucleus and atomic radius decreases.
Down a group, the number of protons increases so nuclear pull increases, but electron shielding increases with the amount of energy levels so valence electrons are repelled and atomic radius increases.
Down a group, ionisation energy decreases.
Traversing a period, first ionisation energy increases.
Traversing a period there are small decreases in first ionisation energy because of sub shells being half or completely full.
D block elements are the transition metals.
F block elements are the lanthanoids and the actinoids
P block elements are groups 13-18 excluding helium.
The halogens are diatomic, non-polar molecules that consist of a single covalent molecule and react to form -1 anions.
Halogens are powerful oxidising agents and have seven valence electrons.
The Boiling point of the halogens increases down the group as the number of shells is increasing so there a more electrons allowing for greater london forces between molecules.
Fluorine and Chlorine are gases at room temperature.
Bromine is a liquid at room temperature
Iodine is a solid at room temperature.
Chlorine is often used in water treatment as it reacts with water to form solutions which kill bacteria. But there are concerns with it forming chlorinated hydrocarbons.
Cl2 + H2O > HCl + HClO
Cl2 + 2NaOH > NaCl + NaClO + H2O
Disproportionation reactions are when a single species is both oxidised and reduced.
If you add acidified silver nitrate to a solution containing halide ions, an insoluble silver salt precipitate will form.
Chloride forms a white precipitate, Bromide forms a cream precipitate, Iodide forms a yellow precipitate.
Chloride precipitate would dissolve in dilute ammonia. Bromide precipitate would dissolve in concentrated ammonia. Iodide precipitate wouldn't dissolve in any form of ammonia.
To Test for carbonate ions, we would add HNO3 and bubble solution through limewater. If carbonate ions are present, we would see effervescence.
To Test for sulfate ions, you would add a solution containing Ba2+ ions (e.g. Barium Nitrate). If present, barium sulfate would form which is a white precipitate.
It is important to carry out the carbonate test before the sulfate, as barium carbonate is also a white precipitate.
Moving down group 2, the alkalinity of the metal hydroxide formed increases, meaning the pH increases and they become more alkaline.
caium Hydroxide is used to neutralise acidic soils.
Magnesium hydroxide and calcium carbonate are used as antacids to neutralise stomach acid.
Helium is the element with the highest first ionisation energy
Sulfur forms a compound with chlorine that has an octahedral shape.
At room temperature and pressure, oxygen has a density of 1.33 x 10^ -3