2.4 Chemical reactions and energy

Cards (6)

  • Exothermic reactions
    • An exothermic reaction is one that transfers energy to the surroundings so the temperature of the surroundings increases
    • Examples of exothermic reactions include combustion, many oxidation reactions and neutralisation
    • Everyday examples of exothermic reactions include self-heating cans (e.g. for coffee) and hand warmers
  • Endothermic reactions
    • An endothermic reaction is one that takes energy in from the surroundings so the temperature from the surroundings decrease
    • Examples of endothermic reactions are thermal decomposition and the reaction of citric acid and sodium hydrogen carbonate
    • Some sports injury packs are based on endothermic reactions
    • Chemical reactions can occur only when reacting particles collide with each other and with sufficient energy
    • Activation energy is the minumum amount of energy that particles must have to react
  • Endothermic reaction energy profile
  • Exothermic reaction energy profile
    • During a chemical reaction:
    1. Energy must be supplied to break bonds in the reactants
    2. Energy is released when bonds in the products are formed
    3. Energy needed to break bonds and energy released whebn bonds are formed can both be calculated from bond energies
    4. Overall energy change = Sum of energy to break bonds - sum of energy released when bonds form
    5. If the overall energy change is negative the reaction is exothermic
    6. If the overall energy change is positive the reaction is endothermic
    • Energy needed to break > energy released ENDOTHERMIC
    • Energy needed to break < energy released EXOTHERMIC