The structures of the acids and the anions

Cards (11)

  • Phosphatic (V) acid is a tetrahedral (bond angle is 109.5°).
  • Phosphoric(V) acid is a triprotic acid, meaning it forms three different anions as the H+H^+ leaves the molecule on reaction with bases. 
  • Sulfuric(IV) acid forms two different salts on removal of one or both of the hydrogen atoms as H+H^+ ions.
  • What is created when SO2SO_2 reacts with water?

    Sulfuric(IV) acid
  • What is created when P4O10P_4O_{10} reacts with water?

    Phosphoric (V) acid
  • Phosphoric acid: Equations
    NaOH+NaOH+H3PO4NaH2PO4+H_3PO_4\rightarrow NaH_2PO_4+H2OH_2O
    NaH2PO4NaH_2PO_4  is sodium dihydrogen phosphate(V), the H2PO4H_2PO_4 ion is the dihydrogen phosphate(V) ion. 
    2NaOH+2NaOH+H3PO4NaH2HPO4+H_3PO_4\rightarrow NaH_2HPO_4+2H2O2H_2O
    NaH2HPO4NaH_2HPO_4  is sodium hydrogen phosphate(V), HPO42HPO_4^{2-} is the hydrogen phosphate(V) ion. 
    3NaOH+3NaOH+H3PO4NaH2PO4+H_3PO_4\rightarrow NaH_2PO_4+3H2O3H_2O
  • Sulfuric(IV) acid: Equations
    Sulfuric(IV) acid forms two different salts on removal of one or both of the hydrogen atoms as H+ ions.
    NaOH+NaOH+H2SO3NaHSO3+H_2SO_3\rightarrow NaHSO_3+H2OH_2O
    NaHSO3NaHSO_3  is sodium hydrogen sulfate(V), the HSO3HSO_3^- ion is the hydrogensulfite ion.
    2NaOH+2NaOH+H2SO3Na2SO3+H_2SO_3\rightarrow Na_2SO_3+2H2O2H_2O
    Na3SO3Na_3SO_3  is sodium hydrogen sulfate(IV), the SO32SO_3^{2-} ion is the sulfate(V) ion.
  • All ions formed by phosphoric acid have a tetrahedral shape (bond angle is 109.5°).
  • All ions formed by sulfuric(IV) acid are pyramidal (bond angle 107.5°).
  • All anions formed by sulfuric(VI) acid are tetrahedral (bond angle 109.5°).
  • Sulfuric(VI) acid: Equations
    NaOH+NaOH+H2SO4NaHSO4+H_2SO_4\rightarrow NaHSO_4+H2OH_2O
    NaHSO4NaHSO_4  is sodium hydrogen sulfate(VI), the HSO4HSO_4^- ion is the hydrogensulfate ion. 
    2NaOH+2NaOH+H2SO4Na2SO4+H_2SO_4\rightarrow Na_2SO_4+2H2O2H_2O
    Na2SO4Na_2SO_4  is sodium sulfate(VI), the SO42SO_4^{2-} ion is the sulfate(VI) ion.