Secondary Cell

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  • are also known as storage cells or accumulators
  • They are galvanic cells whose cell reactions can be reversed by applying an external source of current
  • These can be discharged and recharged many times until the electrode material lasts
  • Examples: Li-ion cell, Ni-Cd battery, Lead-acid battery
  • Battery => a number of galvanic cells connected in series
  • Energy storage of the battery is expressed in ampere-hour (Ah)
  • Cells of same type connected in series, emf is added.
    Cells of same type connected in parallel, emf remains same but internal resistance gets halved; hence, more current can be drawn from the cell without much drop in potential
  • Internal resistance of a cell depends on electrode plate area and cell chemistry.
    It is inversely proportional to electrode plate area
    It is directly proportional to size of the battery