A substance with only one sort of atom is an element.
An atom is the smallest piece of an element that can exist.
A molecule is formed when atoms join together by chemical bonds.
The structure of an atom in terms of the positions, relative masses and relative charges of sub-atomic particles is: proton 1 +1 in the nucleus, neutron 1 0 in the nucleus, electron 1/1836 -1 in shells around nucleus.
Atomic (proton) Number is the number of protons (= number of electrons if it’s an atom, because atoms are neutral).
Mass (nucleon) Number is the number of protons + neutrons.
Isotopes are different atoms of the same element containing the same number of protons but different numbers of neutrons in their nuclei.
Relative atomic mass (of an element) is an average value that takes account of the abundance of the isotopes of the element.
The relative atomic mass of an element (Ar) can be calculated from isotopic abundances.
A sample of chlorine gas is a mixture of 2 isotopes, chlorine-35 and chlorine-37.
These isotopes occur in specific proportions in the sample i.e. 75% chlorine-35 and 25% chlorine-37.
The average mass, or R.A.M. of chlorine can be calculated using the following equation: R.A.M. = (mass of isotope-A x % of isotope-A) + (mass of isotope-B x % of isotope-B) 100.
The relative atomic mass of chlorine in the sample is 35.5.