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higher chemistry
unit 2
oxidation of food
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Cards (11)
primary alcohol -
Hydroxyl
group attached to
carbon
which is
bonded
to
one
other
carbon
secondary alcohols -
hydroxyl
group attached to
carbon
which is bonded to
TWO
other
carbons
tertiary alcohol
- Hydroxyl group attached to
carbon
which is
bonded
to three other carbons
Oxidation of an Alcohol -
Increase in oxygen to hydrogen ratio
Oxidation of primary alcohols -
Primary alcohol
->
aldehyde
->
carboxylic acid
oxidation of secondary alcohols -
Secondary alcohol
->
ketone
oxidation of tertiary alcohols -
No reaction
occurs as there are no
C-H bonds
left to be
broken
Oxidising agents used to determine between aldehydes and ketones
Acidified potassium dichromate
:
orange
-
green
Tollens
reagent
:
blue
-
red
Fehlings
reagent
:
colourless
-
silver
as chain length increases
solubility
decreases
bp
increases
as no of hydroxyl increases
viscosity increases
boiling point increases
as no of branches increases
solubility
decreases
boiling
point
decreases