define periodicity: - patterns or trends across the periodic table which are repeated in other rows.
describe and explain the trend of period 3 elements (atomic radius): DESCRIPTION atomic radius decreases across the period. [1 mark] EXPLANATION - nuclear pull increases (more protons). - outer electrons are more strongly attracted so are drawn in. - shielding is similar. [3 marks]
define first ionisation energy: - amt of energy required to remove one mole of electrons from one mole of gaseous atoms to form one mole of unipositive ions.
describe and explain the trend of first IE in period 3 elements: DESCRIPTION increases across period. EXPLANATION more protons and outer electrons are held more strongly so are more difficult to remove. except Mg to Al- outer electron is further away in p orbital and P to S where there is pairing in p orbital.
describe and explain trend for EN: DESC increases EXP as nuclear pull increases outer electrons are held more strongly.
describe and explain trend for melting point: DESC generaldecrease. EXP - Na to Al = increase (all metallically bonded increasing in strength) - Si forms macromolecular giant covalent structures so is exceptionally strongly bonded. - P to Cl depends on size of molecule and resulting VDW (P4 S8 Cl2). - Ar is the lowest since it is monatomic very low IM forces.
describe and explain conductivity for period 3 elements:
- general decrease
- increase Na to Al- metallicbonds
- more delocalisedelectrons
- all other elements are covalentlybonded so no delocalisedelectrons hence no conductivity.