Electrode Potentials and Electrochemical Cells

Cards (87)

  • Who is the presenter of the video on AQA electrode potentials?
    Chris Harris
  • What is the focus of the video presented by Chris Harris?
    AQA electrode potentials and electrochemical cells
  • What type of chemistry does the video cater to?
    AQA A level chemistry
  • How does this video differ from other resources?
    It specifically covers AQA specifications
  • What additional resources are available on Chris Harris's YouTube channel?
    Revision videos and past paper walkthroughs
  • What is the purpose of the slides available for purchase?
    To provide revision notes and study aids
  • What is the main topic of the video?
    Electrode potentials and electrochemical cells
  • What is a half cell in an electrochemical cell?
    One half of an electrochemical cell
  • What materials can be used to construct a half cell?
    A metal dipped in its ions or platinum electrode
  • What happens when a metal comes into contact with its ions in a half cell?
    A reaction occurs that is in equilibrium
  • What is the equilibrium reaction involving Fe ions?
    Fe<sup>2+</sup> + 2 electrons ⇌ Fe
  • Why is platinum used as an electrode in some half cells?
    It is inert and has good conductivity
  • What is an electrochemical cell made of?
    Two half-cells joined with a wire and salt bridge
  • What does the voltmeter measure in an electrochemical cell?
    The potential difference between two half-cells
  • From where do electrons flow in an electrochemical cell?
    From a more reactive metal to a less reactive one
  • What happens to the zinc electrode during the reaction?
    It gets thinner as zinc converts to ions
  • What occurs at the copper electrode during the reaction?
    Copper ions accept electrons and form copper metal
  • What is the role of the salt bridge in an electrochemical cell?
    To complete the circuit and balance charges
  • What is the standard hydrogen electrode used for?
    To measure standard electrode potential
  • What are the standard conditions for the standard hydrogen electrode?
    298 K and 100 kPa
  • What is the significance of the E<sub>naught</sub> value?
    It indicates how easily a half cell gives up electrons
  • How are electrode potentials typically presented?
    In reduced form with electrons included
  • What does the acronym "no problem" help remember?
    The most negative half cell undergoes oxidation
  • What does the term "redox reaction" refer to?
    A reaction involving reduction and oxidation
  • What happens to the zinc half cell during the reaction?
    Zinc loses electrons and forms zinc ions
  • What is the outcome of combining the half equations for zinc and copper?
    Zinc solid plus copper ions forms zinc ions and copper solid
  • Why can't electrode potentials be measured alone?
    They require a reference like the standard hydrogen electrode
  • What is the purpose of having a reference electrode?
    To allow global comparison of electrode potentials
  • What is the setup for measuring the electrode potential of a copper half cell?
    Hydrogen gas at 298 K and 100 kPa with copper ions
  • What type of half cell is used to measure electrode potential?
    Copper half cell
  • What is the role of the platinum electrode in the setup?
    It serves as the inert conductor for the reaction
  • What are the standard conditions for measuring electrode potential?
    298 Kelvin and 100 kPa
  • Why is the concentration of H+ ions important in the setup?
    It must be 1 mole per dm³ for accuracy
  • What concentration of copper ions is required in the beaker?
    1 mole per dm³
  • What is the significance of using hydrochloric acid in the setup?
    It produces 1 mole per dm³ of H+ ions
  • How does sulfuric acid differ from hydrochloric acid in terms of H+ ion concentration?
    It produces two H+ ions per molecule
  • What is the electrochemical series?
    A table of half cell reactions and potentials
  • How are half cell reactions displayed in the electrochemical series?
    In reduced form with electrons included
  • What does a positive value in the electrochemical series indicate?
    It indicates a strong tendency to gain electrons
  • What is oxidation in terms of electron transfer?
    Loss of electrons