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AP Chemistry
Unit 9: Thermodynamics and Electrochemistry
9.1 Introduction to Entropy
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What does entropy measure in thermodynamics?
Disorder or randomness
Entropy increases in
spontaneous
processes.
True
Match the state of matter with its entropy level:
Crystalline solid ↔️ Low
Liquid ↔️ Moderate
Gas ↔️ High
Arrange the following processes in terms of increasing entropy change:
1️⃣ Ice forming ||| Water freezing ||| Gas compressing
2️⃣ Ice melting ||| Gas expanding
The second law of thermodynamics states that entropy of an isolated system decreases over time.
False
What type of processes require energy input to occur?
Non-spontaneous
Spontaneous processes decrease the entropy of a system.
False
A system with low entropy has a greater number of possible arrangements of its particles.
False
Arrange the states of matter in terms of increasing entropy:
1️⃣ Solid
2️⃣ Liquid
3️⃣ Gas
A system with high entropy has fewer possible arrangements of its particles.
False
A crystalline solid is an example of a system with low disorder and low
entropy
The second law of thermodynamics states that the entropy of an isolated system not in equilibrium will tend to
increase
Match the process with the entropy change it produces:
Spontaneous ↔️ Increases entropy
Non-spontaneous ↔️ Decreases entropy
Spontaneous processes lead to greater
disorder
What is the equation for calculating changes in entropy?
Δ
S
=
\Delta S =
Δ
S
=
q
T
\frac{q}{T}
T
q
The entropy change when ice melts at
0°C
is positive.
True
The formation of water from hydrogen and oxygen leads to a decrease in
entropy
.
True
The unit of entropy is
J/K
What does disorder refer to in the context of entropy?
Lack of structure
A system with high entropy has a greater number of possible
arrangements
The increase in entropy during spontaneous processes drives the natural tendency towards
disorder
What symbol denotes entropy?
S
Match the system with its disorder and entropy level:
Highly structured ↔️ Low
Organized ↔️ Moderate
Completely random ↔️ High
In the context of entropy, disorder refers to randomness or lack of
structure
Match the level of order with the corresponding entropy level:
Highly structured ↔️ Low entropy
Organized ↔️ Moderate entropy
Completely random ↔️ High entropy
A gas has high disorder and high
entropy
.
True
What type of process increases the entropy of a system?
Spontaneous
Non-spontaneous processes require energy input to occur.
True
The tendency for entropy to increase is a fundamental principle of
thermodynamics
.
True
In the entropy change equation, 'q' represents the heat absorbed or
released
What type of reactions are more likely to occur spontaneously based on entropy changes?
Δ
S
>
0
\Delta S > 0
Δ
S
>
0
Match the factor affecting entropy change with its effect:
Change in Physical State ↔️ Solid → Liquid → Gas increases entropy
Temperature Increase ↔️ Higher temperature increases entropy
Molecular Complexity ↔️ More complex molecules increase entropy
What does understanding entropy changes help predict in chemical reactions?
Favorability
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