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3.2 Inorganic Chemistry
3.2.5 Transition Metals (A-level only)
3.2.5.4 Redox Reactions
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Cards (100)
What is a redox reaction defined as?
Change in oxidation number
In the reaction `Cu(s) + 2AgNO₃(aq) → Cu(NO₃)₂(aq) + 2Ag(s)`, copper is
oxidized
What is the definition of oxidation in redox reactions?
Loss of electrons
Where are electrons added to balance the charge in a reducing half-equation?
Left side
What does a reducing half-equation show in terms of electron transfer?
Gain of electrons
The half-equation Fe²⁺(aq) →
Fe³⁺
(aq) represents oxidation.
True
In basic conditions, OH⁻ ions are added to neutralize excess
H⁺
Match the half-equation type with its characteristic:
Oxidizing Half-Equation ↔️ Electrons appear on the right side
Reducing Half-Equation ↔️ Electrons appear on the left side
Where are electrons located in a reducing half-equation?
Left side
Redox reactions involve the transfer of
electrons
.
True
Oxidation involves the loss of electrons and an increase in
oxidation
number.
True
What happens to the oxidation number of silver ions (Ag⁺) during the reaction?
Decreases from +1 to 0
Reduction involves the gain of electrons and a decrease in oxidation
number
Multiplying half-equations by appropriate factors ensures the number of
electrons
is equal.
True
In an oxidizing half-equation, a species loses electrons.
True
What is added to the left side of the reduction half-equation in acidic conditions to balance oxygen atoms?
H₂O
What happens to the oxidation number during reduction?
It decreases
When balancing atoms in a half-equation, oxygen and
hydrogen
are balanced last.
True
Oxidation is defined as an increase in
oxidation
number.
Match the concept with its definition:
Oxidation ↔️ Increase in oxidation number, loss of electrons
Reduction ↔️ Decrease in oxidation number, gain of electrons
What happens to the oxidation number during oxidation?
It increases
When balancing atoms in half-equations, oxygen and hydrogen are balanced last.
True
Steps in the half-equation method for balancing redox equations
1️⃣ Write the unbalanced redox equation
2️⃣ Separate into half-equations
3️⃣ Balance the atoms except oxygen and hydrogen
4️⃣ Balance oxygen and hydrogen
5️⃣ Balance the charge
6️⃣ Equate the number of electrons
7️⃣ Combine and simplify
Why is it necessary to equate the number of electrons in half-equations?
To combine the equations
Hydrogen is balanced by adding H⁺ to the opposite side where
H₂O
was added.
True
Steps to balance the reduction half-equation in the example reaction `MnO₄⁻(aq) → Mn²⁺(aq)`
1️⃣ Balance Mn atoms
2️⃣ Balance oxygen by adding H₂O
3️⃣ Balance hydrogen by adding H⁺
4️⃣ Balance the charge with electrons
In acidic solutions, hydrogen is balanced by adding
H⁺
ions.
True
The oxidation half-equation for iron(II) to iron(III) is
Fe²⁺
How many hydrogen ions are added to balance hydrogen in the reduction half-equation for permanganate?
8
What method is used to balance complex redox equations by separating them into oxidation and reduction half-equations?
Half-equation method
Hydrogen ions (H⁺) are added to balance hydrogen in acidic conditions.
True
Transition metal ions can act as either oxidizing or reducing agents due to their variable
oxidation states
.
True
What is the half-equation for the oxidation of a metal ion M²⁺ to M³⁺?
M^{2+}(aq) \rightarrow M^{3+}(aq) + e^{-}</latex>
In the reaction Cu(s) + 2AgNO₃(aq) → Cu(NO₃)₂(aq) + 2Ag(s), which substance is oxidized?
Copper
In a redox reaction, reduction involves the gain of
electrons
Combining the half-equations involves canceling out common
species
The half-equation method is a systematic way to balance complex redox equations.
True
What is the unbalanced redox equation in the example given?
MnO₄⁻(aq) + Fe²⁺(aq) → Mn²⁺(aq) + Fe³⁺(aq)
Match the half-equation type with its definition:
Oxidizing Half-Equation ↔️ Shows the loss of electrons
Reducing Half-Equation ↔️ Shows the gain of electrons
In the reaction between Fe²⁺ and MnO₄⁻, Fe²⁺ acts as the
reducing agent
.
True
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