Kinetics

Cards (92)

  • What is the activation energy (EA)?
    Minimum energy needed for a reaction
  • What does the Maxwell-Boltzmann energy distribution illustrate?
    Spread of energies in gas or liquid
  • Why does the energy distribution curve go through the origin?
    There are no molecules with no energy
  • Why should the energy distribution curve never meet the x-axis?
    There is no maximum energy for molecules
  • Where is the mean energy of particles located on the curve?
    Not at the peak of the curve
  • What does the area under the Maxwell-Boltzmann curve represent?
    Total number of particles present
  • Why do a few particles have low energies?
    Collisions cause some particles to slow down
  • How many particles typically have energy greater than the activation energy?
    Only a few particles have energy > EA
  • What is the Emp in the context of energy distribution?
    Most probable energy of particles
  • What happens to the energy distribution as temperature increases?
    More molecules have higher energies
  • What remains constant when temperature increases in the energy distribution?
    Total area under the curve remains constant
  • How does the range of energies change with temperature?
    Molecules have a wider range of energies
  • What happens to the Emp and mean energy at higher temperatures?
    Both shift to higher energy values
  • What is required for reactions to occur?
    Collisions with sufficient energy
  • What is the usual unit for measuring the rate of reaction?
    mol dm<sup>-3</sup>s<sup>-1</sup>
  • How is the rate of reaction determined from a concentration vs. time graph?
    Gradient of the curve indicates the rate
  • What is the initial rate of a reaction?
    Rate at the start of the reaction
  • What topic is the video about?
    Kinetics
  • How can reaction rates be calculated from graphs?
    By drawing a tangent and calculating gradient
  • What effect does increasing concentration have on reaction rates?
    Increases frequency of effective collisions
  • How is kinetics related to rates of reaction?
    Kinetics is comparable to rates of reaction
  • How does the shape of the energy distribution curve change with increased concentration?
    Curves become higher, area increases
  • What must happen for a reaction to occur?
    A and B must collide
  • What happens to the number of molecules with energy > EA when concentration increases?
    More molecules have energy > EA
  • What are the two outcomes of a collision between reactants?
    Nothing happens or a reaction occurs
  • What is the activation energy?
    Minimum energy required for a reaction
  • How do different volumes of the same initial concentrations affect reaction rates?
    Same initial rate, different final amounts
  • How is activation energy similar to a fee?
    It's the cost to initiate a reaction
  • What factors increase the rate of reaction?
    Higher concentration, temperature, surface area
  • What does a qualitative graph of a reaction show?
    Reaction progress over time without numbers
  • How is the reaction rate measured in the sodium thiosulfate and hydrochloric acid experiment?
    As 1/time for cross disappearance
  • What happens to the reaction rate if the concentration is halved?
    The reaction rate decreases
  • Why is measuring 1/time an approximation for reaction rate?
    It does not include concentration
  • What effect does increasing surface area have on reaction rates?
    Increases frequency of successful collisions
  • How does increasing concentration affect collisions?
    More particles lead to more collisions
  • What does a steeper line on a reaction graph indicate?
    A faster reaction rate
  • What is the definition of a catalyst?
    Increases reaction rates without being used
  • What effect does higher temperature have on reaction rates?
    Increases energy and frequency of collisions
  • How do catalysts increase reaction rates?
    By providing an alternative route with lower EA
  • What is the Maxwell-Boltzmann distribution curve used for?
    To show energy distribution of particles