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A level chemistry
Physical 1
Kinetics
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Cards (92)
What is the activation energy (EA)?
Minimum energy needed for a
reaction
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What does the Maxwell-Boltzmann energy distribution illustrate?
Spread of energies in
gas or liquid
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Why does the energy distribution curve go through the origin?
There are no
molecules
with no energy
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Why should the energy distribution curve never meet the x-axis?
There is no maximum energy for
molecules
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Where is the mean energy of particles located on the curve?
Not at the
peak
of the curve
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What does the area under the Maxwell-Boltzmann curve represent?
Total number of
particles
present
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Why do a few particles have low energies?
Collisions
cause some particles to slow down
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How many particles typically have energy greater than the activation energy?
Only a few particles have energy >
EA
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What is the Emp in the context of energy distribution?
Most probable energy of
particles
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What happens to the energy distribution as temperature increases?
More
molecules
have higher energies
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What remains constant when temperature increases in the energy distribution?
Total area under the
curve
remains constant
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How does the range of energies change with temperature?
Molecules
have a wider range of energies
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What happens to the Emp and mean energy at higher temperatures?
Both
shift to
higher
energy values
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What is required for reactions to occur?
Collisions
with
sufficient
energy
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What is the usual unit for measuring the rate of reaction?
mol dm<sup>-3</sup>s<sup>-1</sup>
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How is the rate of reaction determined from a concentration vs. time graph?
Gradient
of the curve indicates the rate
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What is the initial rate of a reaction?
Rate
at the
start
of the reaction
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What topic is the video about?
Kinetics
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How can reaction rates be calculated from graphs?
By drawing a tangent and calculating
gradient
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What effect does increasing concentration have on reaction rates?
Increases frequency of
effective collisions
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How is kinetics related to rates of reaction?
Kinetics is
comparable
to rates of reaction
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How does the shape of the energy distribution curve change with increased concentration?
Curves become
higher
, area
increases
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What must happen for a reaction to occur?
A and B must
collide
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What happens to the number of molecules with energy > EA when concentration increases?
More
molecules
have
energy
>
EA
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What are the two outcomes of a collision between reactants?
Nothing happens or a reaction
occurs
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What is the activation energy?
Minimum energy required for a
reaction
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How do different volumes of the same initial concentrations affect reaction rates?
Same
initial rate, different
final
amounts
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How is activation energy similar to a fee?
It's the cost to
initiate
a reaction
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What factors increase the rate of reaction?
Higher
concentration
,
temperature
,
surface area
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What does a qualitative graph of a reaction show?
Reaction progress over time without
numbers
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How is the reaction rate measured in the sodium thiosulfate and hydrochloric acid experiment?
As 1/
time
for cross
disappearance
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What happens to the reaction rate if the concentration is halved?
The
reaction rate
decreases
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Why is measuring 1/time an approximation for reaction rate?
It does not include
concentration
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What effect does increasing surface area have on reaction rates?
Increases frequency of
successful collisions
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How does increasing concentration affect collisions?
More
particles
lead to more collisions
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What does a steeper line on a reaction graph indicate?
A faster
reaction rate
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What is the definition of a catalyst?
Increases
reaction rates
without being used
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What effect does higher temperature have on reaction rates?
Increases
energy
and
frequency
of
collisions
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How do catalysts increase reaction rates?
By providing an alternative route with lower
EA
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What is the Maxwell-Boltzmann distribution curve used for?
To show
energy distribution
of particles
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