kinetic molecular theory a model used to explain the behavior of matter.
1. Matter is made of particles that are constantly in motion. This
energy in motion is called kinetic energy.
The amount of kinetic energy in a substance is related to its temperature.
There is space between particles. The amount of space in between
particles is related to the substance’s state of matter.
Phase changes happen when the temperature of the substance changes
sufficiently.
Liquid has a definite volume, because molecules in a liquid do
not break away from the attractive forces. The molecules can, however, move past one another
freely, and so a liquid can flow, can be poured, and
assumes the shape of its container.
Solid Molecules are held rigidly in position with virtually little freedom of motion.
Many solids are characterized by long-range order; that
is, the molecules are arranged in regularconfigurations in three dimensions.
Ionic Bond • bond formed between metals and
non-metals
• transfer of e-
• forms ionic compounds
Covalent Bond • bond formed between non-metals
• sharing of e-
• forms molecular compounds
Intramolecular forces are the forces that hold atoms together within a molecule
Intermolecular forces are forces that exist between molecules.
Cation- a positively charged ion.
Anion- a negatively charged ion.
Polar molecule– is a type of molecule that has a separation of
electric charge, where one side of the molecule is positively
charge and the other side is negatively charged.
Nonpolar molecule– has no separation of charge, so no positive or negative poles are formed.
Dipole– refers to a molecule that possesses a delocalized positive
and negative charge.
Ion-Dipole forces occur between an ion a polar molecule.
Melting point (MP) - The temperature at which a solid substance melts into its liquid state.
ION-DIPOLE INTERACTION
, These interactions are similar to dipole-dipole interactions except for the fact that they arise between ions and polar molecules.
2. HYDROGEN BOND
¡Hydrogen Bond is a special type of dipole-dipole
interaction between the
hydrogen atom in a polar
bond, such as N‒H, O‒H, or
F‒H, and an electronegative
O, N, or F atom.
Hydrogen bonds between
water molecules are particularly strong.
Dipole-dipole interactions are attractive forces among polar molecules.
The partially positive portion of one molecule is attracted to the partially negative
portion of another molecule
Dipole-dipole is a force of attraction between oppositely charged ends of polar
molecules.
Permanent dipole – refers to the dipole moment that originally occurs in a
compound due to uneven electron distribution.
Instantaneous dipole –separation of charges in a non-polar molecule at an
instant due to sudden disturbance in the electric cloud around the molecule
Induced dipole – refers to the dipole moment created in a nonpolar compound
due to the effect of an ion nearby.
LONDON DISPERSION , It operates for a short distance and it is the weakest force.
London dispersion occur when there is an instantaneous dipole-induced dipole interaction between
molecules.
The weakest IMFA and occurs in non-polar molecules.
The strongest is the Ion-dipole forces, are attractive forces that occur between an ion and
a polar molecule.
Next is the Hydrogen bond, it is a special type of dipole-dipole interaction between the
hydrogen atom in a polar bond, such as N‒H, O‒H, or F‒H, and an electronegative O, N, or
F atom.
Another type of attracted forces is Dipole-dipole forces, are attractive forces between
polar molecules (molecules that possess dipole moments)
The weakest is the London Dispersion Forces, these forces of attraction result from
temporary dipole moments induced in ordinarily nonpolar molecules.
intramolecular forces are weaker
intermolecular forces are stronger
intermolecular determine their state of matter and physicalproperties
intramolecular determine the chemicalbehavior of the substance