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Edexcel A-Level Chemistry
Core Practicals
CP1 Measuring the Molar Volume of a Gas
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What is the definition of molar volume of a gas?
Volume occupied by one mole
At STP, the molar volume of an ideal gas is approximately
22.4
dm³/mol.
The round-bottom flask is used to contain the reaction
mixture
What is the purpose of a gas syringe in measuring molar volume?
To measure gas volume
Steps in the experimental procedure to measure molar volume of a gas
1️⃣ Position the clamp stand and attach the round-bottom flask, ensuring it is connected to the gas syringe via tubing and sealed with a bung.
2️⃣ Prepare Reactants: Measure the appropriate volume of liquid using a measuring cylinder and weigh the solid reactant using a balance.
3️⃣ React Mix: Add the liquid to the round-bottom flask, then introduce the solid reactant. Quickly seal the bung.
4️⃣ Collect Gas: Allow the reaction to proceed until no more gas is produced, capturing the gas in the syringe.
5️⃣ Record Readings: Measure the volume of gas collected and note the mass of the solid reactant used.
6️⃣ Calculate Molar Volume: Divide the volume of gas produced by the number of moles of the reactant used.
7️⃣ Repeat: Conduct multiple trials and calculate the average molar volume.
Why is the molar volume of an ideal gas approximately 22.4 dm³/mol at STP?
Gas particles are far apart
Match the equipment with its purpose in measuring molar volume:
Round-bottom flask ↔️ Contains the reaction mixture
Gas syringe ↔️ Measures gas volume
Balance ↔️ Weighs reactants
Measuring cylinder ↔️ Measures liquid volumes
The formula to calculate molar volume is
V_{m} = \frac{V}{n}
What formula is used to calculate the number of moles (n) of a solid reactant?
n
=
n =
n
=
m
M
\frac{m}{M}
M
m
1 dm³ is equal to 1000
cm³
.
What is the molar mass of magnesium (Mg)?
24.3 g/mol
To calculate the number of moles of 2.4 g of magnesium, you divide the mass by its
molar
mass.
Steps to calculate molar volume from data
1️⃣ Calculate the number of moles (n) using the formula
n
=
n =
n
=
m
M
\frac{m}{M}
M
m
.
2️⃣ Divide the volume (V) by the number of moles (n) using the formula
V
m
=
V_{m} =
V
m
=
V
n
\frac{V}{n}
n
V
.
3️⃣ Convert units if needed, such as changing cm³ to dm³ by dividing by 1000.
1000 cm³ is equal to 1
dm³
.
What is the molar volume of hydrogen gas produced when 2.4 g of magnesium reacts to produce 1000 cm³ of gas?
10.13 dm³/mol
What are the units for molar volume?
dm³/mol or cm³/mol
In the formula for molar volume,
n
n
n
represents the number of moles
What is the formula to calculate the number of moles (n)?
n
=
n =
n
=
m
M
\frac{m}{M}
M
m
Steps to calculate molar volume
1️⃣ Calculate the number of moles (n)
2️⃣ Divide the volume (V) by the number of moles (n)
3️⃣ Convert units if needed
1 dm³ is equal to 1000
cm³
In the example provided, what is the molar mass of magnesium (Mg)?
24.3 g/mol
In the example, the number of moles of Mg is approximately
0.0987
What is the molar volume of hydrogen gas in the example?
10.13
dm
3
/
mol
10.13 \text{ dm}^{3} / \text{mol}
10.13
dm
3
/
mol
Temperature fluctuations can affect the
volume
of a gas
What is the definition of molar volume of a gas?
Volume per mole
At standard temperature and pressure (STP), the molar volume of an ideal gas is approximately
22.4
dm
3
/
mol
22.4 \text{ dm}^{3} / \text{mol}
22.4
dm
3
/
mol
What is the purpose of a round-bottom flask in the experiment?
Contains reaction mixture
A balance is used to accurately weigh
reactants
in the experiment
Which apparatus is used to collect and measure gas volume?
Gas syringe
The round-bottom flask should be mounted on a
clamp
What two tools are used to prepare reactants?
Measuring cylinder and balance
Steps to measure the molar volume of a gas
1️⃣ Position Setup: Mount the round-bottom flask
2️⃣ Prepare Reactants: Measure liquid volume and weigh solid reactant
3️⃣ React Mix: Add liquid to flask, then solid reactant
4️⃣ Collect Gas: Allow reaction to complete
5️⃣ Record Readings: Measure gas volume and reactant mass
6️⃣ Calculate Molar Volume: Use the formula
7️⃣ Repeat: Conduct multiple trials and calculate the average
The formula to calculate molar volume is
V_{m} = \frac{V}{n}
The apparatus for this experiment includes a gas syringe, clamp stand, and bung with a
gas-tight seal
.
When gathering data, you should record the volume of gas collected and the mass of the solid reactant used in the following
table
Match the measurement with its corresponding unit.
Volume of gas ↔️
dm
3
\text{dm}^{3}
dm
3
or
cm
3
\text{cm}^{3}
cm
3
Mass of solid reactant ↔️
g
\text{g}
g
To calculate the number of moles, use the formula
n = \frac{m}{M}
1 dm³ is equal to 1000
cm³
.
Gas leakage during the experiment can lead to an
underestimation
What is the molar volume of an ideal gas at STP?
22.4 \text{ dm}^{3} / \text{mol}</latex>
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