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Topic 2: Bonding and Structure
2.4 Intermolecular Forces
2.4.1 Types of Intermolecular Forces
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What are intermolecular forces?
Forces between molecules
Intermolecular forces are stronger than bonds within molecules.
False
Match the force type with its relative strength:
Covalent Bonds ↔️ Strong
Intermolecular Forces ↔️ Weak
What physical properties are influenced by intermolecular forces?
Boiling points and viscosity
Intermolecular forces are weaker than bonds within
molecules
What are the three main types of intermolecular forces?
London Dispersion, Dipole-Dipole, Hydrogen
Between what molecules do London Dispersion Forces act?
All molecules
London Dispersion Forces arise from temporary fluctuations in electron
distribution
Dipole-Dipole Forces are stronger than
London Dispersion Forces
.
What molecules must be present for hydrogen bonding to occur?
H bonded to O, N, or F
Hydrogen bonding involves strong attraction between a hydrogen atom and a lone pair of electrons on an electronegative
atom
What type of intermolecular force acts between all molecules and is the weakest?
London Dispersion Forces
What type of intermolecular force acts only between polar molecules and is moderate in strength?
Dipole-Dipole Forces
Hydrogen bonds are the strongest type of
intermolecular
force.
What creates temporary dipoles in London Dispersion Forces?
Electron fluctuations
What is the strength of London Dispersion Forces proportional to?
1
r
6
\frac{1}{r^{6}}
r
6
1
London Dispersion Forces arise from temporary fluctuations in electron
distribution
London Dispersion Forces are the strongest type of intermolecular force.
False
Match the type of intermolecular force with its relative strength:
London Dispersion ↔️ Weakest
Dipole-Dipole ↔️ Moderate
Hydrogen Bonds ↔️ Strongest
What type of intermolecular force acts between all molecules, whether polar or nonpolar?
London Dispersion Forces
London Dispersion Forces arise from temporary fluctuations in electron
distribution
London Dispersion Forces are the weakest type of
intermolecular
force.
What type of molecules can form hydrogen bonds?
Molecules with H bonded to O, N, or F
Intermolecular forces are weaker than bonds within
molecules
Match the type of force with its description:
Covalent Bonds ↔️ Forces within molecules
Intermolecular Forces ↔️ Forces between molecules
The strength of London Dispersion Forces is inversely proportional to the
sixth
power of the distance between molecules.
What are the three main types of intermolecular forces?
London Dispersion, Dipole-Dipole, Hydrogen Bonds
Order the intermolecular forces from weakest to strongest:
1️⃣ London Dispersion Forces
2️⃣ Dipole-Dipole Forces
3️⃣ Hydrogen Bonds
What causes London Dispersion Forces in all molecules?
Temporary fluctuations in electron distribution
London Dispersion Forces are present in both
polar
and nonpolar molecules.
Dipole-Dipole Forces occur between polar molecules with permanent
dipoles
What type of attraction causes dipole-dipole forces?
Attraction between permanent dipoles
Dipole-Dipole Forces are stronger than
London Dispersion Forces
.
Under what conditions does hydrogen bonding occur?
H bonded to O, N, or F
Hydrogen bonding involves a hydrogen atom and a lone pair of electrons on an electronegative
atom
Hydrogen bonds are stronger than dipole-dipole forces but weaker than London Dispersion Forces.
False
Which intermolecular force is the strongest?
Hydrogen Bonds