atomic structure

Cards (69)

  • what is the charge on electrons
    1-
  • what is the mass of electrons
    1/1840
  • where are electrons found
    shell
  • what is the mass of protons
    1+
  • what is the mass of protons
    1
  • where are protons found
    nucleus
  • what is the mass of neutrons
    1
  • what is the charge of neutrons
    0
  • where are neutrons found
    nucleus
  • what is the atomic number
    the total number of protons and neutrons in the nucleus of an atom
  • what is the atomic mass number
    the total number of protons and neutrons in the nucleus of an atom
  • define isotopes in terms of atomic and mass number
    atoms of the same element with the same atomic number but a different mass number
  • define isotopes in terms of particles
    atoms of the same element with the same number of protons but a different number of neutrons
  • how does light bend in a mass spectrometer
    the lightest element bends the most with the heaviest element bending the least
  • what is the purpose of a mass spectrometer
    the determine the relative atomic mass of elements, isotopic composition and identify unknown compounds
  • label this mass spectrometer graph
    labels
    A) no of bars = no of isotopes
    B) base peak
    C) molecular ion peak
  • what is the equation for calculating RAM using mass spectra
    RAM = (% abundance x relative isotopic mass)
  • how is the most abundant isotope arranged
    nelement+^ n element ^ +
  • what causes fragmentation of a diatomic element i.e Cl2
    fast moving electrons
  • how many peaks would Cl2 have and what combinations?
    3 peaks. 35-35, 37-37, 35-37
  • what is m/z
    mass / charge
  • what is the base peak
    the most abundant species, also the most stable
  • what is the molecular ion peak
    the molecule that has lost an electron but has no broken up - reminds us that isotopes exist
  • what is the m + 1 peak
    the smaller peak beside the molecular ion peak
  • how many electrons can an s orbital hold
    2
  • how many electrons can a p orbital hold
    6
  • how many electrons can a d orbital hold
    10
  • how many electrons can an f orbital hold
    14
  • write spdf notation
    1s2 2s2 2p6 3s2 3p6 3d10 4s2
  • why does 4s empty and fill before 3d
    it is slightly closer to the nucleus
  • how is spdf notation drawn
    with all 'up' drawn in orbitals before the 'down'
  • spdf notation drawn
  • what are the s block elements
    group 1 and 2 plus helium
  • what are the p block elements
    groups 3,4,5,6,7,0
  • what are the d block elements
    transition metals
  • what are the f block elements
    lactinides and actinides
  • what is the trend in first ionisation energies across a period
    increase
  • why do first ionisation energies increase across a period
    nuclear charge increases
    shielding remains almost constant
    atomic radius decreases
    most outer electron is closer to the pull of the attractive nucleus, which requires more energy to remove
  • what is the trend in first ionisation energies down a group
    decreses
  • why do first ionisation energies decrease down a group
    whilst nuclear charge increases
    more than offset by an increase in shielding (due to an increase in the number of inner shells)
    atomic radius decreases
    outer shell electron is further from attractive pull of the nucleus
    requires less energy to remove