Define isotope Atoms of the same element with different number of neutrons and different masses.
Define relative atomic mass (Ar) Weighted mean mass of an atom of the element compared with 1/12th mass of an atom of carbon-12, which has a mass of 12.
Define relative isotopic mass The mass of an isotope compared with 1/12th mass of an atom of carbon-12, which has a mass of 12.
What does a mass spectrometer measure? The mass of isotopes
How does a mass spectrometer work? Atoms are converted into positive ions.Magnetic field is applied.Deflects positive ions.Ions are separated and can be detected.
What does the amount of deflection in a mass spectometer depend on? size of particle (heavier deflected less)charge (bigger charges deflected more)
Equation for relative atomic mass." Ar= isotopic mass x relative abundance + isotopic mass x relative abundance / total abundance
Define chemical bond A force that holds particles together in a material
Define simple covalent structure 2 or more non-metal atoms bonded together
Giant metallic The metal elements of the periodic table
Define covalent bond The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
What happens during covalent bonding? Each atom donates a valence electron to the bond.
Define dative bond A covalent bond where only one of the bonded atoms donates both electrons being shared.
Examples of molecules with dative bonds. Boron trifluoride/ammonia complex
Electron pair repulsion theory: shape of simple molecule/ion is determined by number of bonding pairs + lone pairs repel eachother so they are as far apart as possible
Name of shape with 2 bonding pairs Linear
Name of shape with 3 bonding pairs Trigonal planar
Name of shape with 4 bonding pairs Tetrahedral
Name of shape with 6 bonding pairs Octahedral
Bond angle of shape with 2 bonding pairs 180 degrees
Bond angle of shape with 3 bonding pairs 120 degrees
Bond angle of shape with 4 bonding pairs 109.5 degrees
Bond angle of shape with 6 bonding pairs 90 degrees and 180 degrees
3-D drawing of linear molecule "
3-D drawing of tetrahedral "
3-D drawing of octahedral "
Shape and angle between 4 bonding pair and 0 lone pairs 109.5 degrees - tetrahedral
Shape and angle between 3 bonding pair and 1 lone pair 107 degrees - pyramidal
Shape and angle between 2 bonding pair and 2 lone pairs 104.5 degrees - V shaped
What is a induced dipole-dipole interaction Temporary, induced dipole-dipole forces that occur between non-polar molecules.
The strength of induced dipole-dipole interactions increases as the number of electrons increase the surface contact increases
Define electronegativity The ability of an atom to attract the bonding pair of electrons in a covalent bond.
How do polar molecules occur? When atoms with different electronegativities bond, have permanent dipoles and the molecule is 'unsymmetrical'.
What is a permanent dipole? When in covalent bonds between different atoms, one atom has a stronger attraction for the shared electrons than the other does. (Substantially different electronegativity)
Define a symmetrical molecule. All the atoms around the central atom are the same and there are no lone pairs on the central atom.
Why do symmetrical molecules not have a overall dipole? The dipoles cancel out.
Define an unsymmetrical molecule. When the central atom has two or more different atoms attached and the central atom has one or more lone pairs.
Is water polar? Yes because: unsymmetrical - dipoles don't cancel outoxygen more elctronegative than hydrogen