SC18 - Rates of Reaction

Subdecks (4)

Cards (39)

  • The rate of a reaction is a measure of how quickly a reactant is used up, or a product is formed
  • For a chemical reaction to happen:
    • Reactant particles must collide with each other
    • The particles must have enough energy for them to react
  • A collision that produces a reaction is called a successful collision
  • Activation energy is the minimum amount of energy needed for a collision to be successful. This is different for different reasons
  • There are different ways to determine the rate of a reaction, depending on the reactants and products involved, and how easy it is to measure changes in them
  • How long a reaction is observed for depends on the rate of reaction, which can vary from being almost instantaneous to taking years to complete
  • In the lab, reactions are usually followed over a few seconds or minutes
  • Measuring mass:
    • Change in mass of a reactant or product can be followed during a reaction
    • Useful when carbon dioxide is a product leaving the reaction container
    • Not suitable for hydrogen and other gases with a small relative formula mass, Mr
    • Units for rate are usually g/s or g/m
  • Measuring volume:
    • Change in volume of a reactant or product can be followed during a reaction
    • This method is used when a gas leaves the reaction container
    • Volume of a gas is measured using a gas syringe, or an upside down burette or measuring cylinder
    • Units for rate are usually cm3/s or cm3/min
  • The rate of reaction can be analysed by plotting a graph of mass or volume of product formed against time. The graph shows this for two reactions.
    The gradient of the line is equal to the rate of reaction:
    • the steeper the line, the greater the rate of reaction
    • fast reactions finish sooner (when the line becomes horizontal) than slow reactions