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Chemistry
Acids, Bases and Salts
Concepts (A,B,S)
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acid + carbonate ->
salt
+
carbon dioxide
+
water
An acid is a substance that produces
hydrogen
ions (
H+
) when dissolved in
water.
A strong acid undergoes
complete dissociation
in water
A weak acid undergoes
partial dissociation
in water
The basicity of an acid is the number of
hydrogen ions
that can be produced
per molecule of acid
when dissolved in
water.
strong acids ->
HCL
,
H2SO4
,
HNO3
,
Weak acids ->
H3PO4
,
H2CO3
,
CH3COOH
Water
must be present before acids exhibit their acidic properties as it lets acids
ionise
to form
H+
ions
The strength of an acid is based on its
degree
of
ionisation
in
water
Acid + Metal ->
Salt
+
Hydrogen Gas
Acid + Base/
Alkali
->
Salt
+
water
A
base
is a
metal oxide
,
hydroxide
or
aqueous ammonia
which reacts with an
acid
to give
salt
and
water
only
An
alkali
is a
soluble base.
When dissolved in
water
, it produces
hydroxide ions
(
OH-
) in solution.
Neutralisation
is the process whereby an
acid
reacts with a
base
to form a
salt
and
water
only.
A strong alkali undergoes
complete ionisation
in water
A weak alkali undergoes
partial ionisation
in water
base +
acidic oxide
-> salt
base + ammonium salt ->
salt
+
water
+
ammonia
Lime/
Quicklime
is
calcium oxide
,
CaO
(
s
)
Slaked lime is
calcium hydroxide
,
Ca(OH)2
(
s
)
Limewater is
calcium hydroxide
,
Ca(OH)2
(
aq
)
Limestone/marble/chalk is
calcium carbonate
,
CaCO3
(
s
)
The 4 types of oxides are
acidic
,
basic
,
amphoteric
and
neutral
Basic oxides: react with
acids
to form
salt
and
water
;
Na2O
,
MgO
,
CuO
Amphoteric oxides: reacts with both
acids
and
alkalis
to form
salt
and
water
;
ZnO
,
Al2O3
,
PbO
Acidic oxides: reacts with
bases
to form
salt
and
water
;
SO2
,
CO2
,
NO2
Neutral oxides: has no effect on litmus;
NO
,
CO,
H2O
All
Sodium,
Potassium
and
Ammonium
salts are soluble
All nitrate salts are
soluble
All halides (
group 17
) are
soluble
except
lead
and
silver.
All sulfates are
soluble
except
calcium
,
barium
and
lead
All carbonates are
insoluble
except
sodium
,
potassium
and
ammonium
All hydroxides and oxides are
insoluble
except
sodium
,
potassium
and
ammonium
Preparation of soluble salts:
Titration
and
adding excess insoluble solid to a fixed volume of acid
Preparation of insoluble salts:
precipitation
methyl orange will turn from orange to red in acids and yellow in alkalis
screened methyl orange will turn from
green
to
grey
in
acids
and
green
in
alkalis