Lipids

Cards (13)

  • Lipids
    Have large amounts of carbon and hydrogen and smaller amounts of oxygen
  • Lipids
    • Insoluble in water as they are non-polar, but can dissolve in alcohol
  • Types of lipids
    • Triglycerides
    • Phospholipids
    • Steroids
  • Triglycerides
    Made up of glycerol and fatty acids
  • Glycerol
    • 3 carbon atoms, has an alcohol, there's a free —OH group, important to structure of triglycerides
  • Fatty acids
    • Have a carboxyl group (—COOH) attached to a hydrocarbon tail, from 2-20 carbons long
    • The carboxyl group ionises into a H⁺ and a -COO⁻ group, so it is an acid and can product free H⁺ ions
  • Saturated fatty acid

    Has no C=C bonds
  • Mono-saturated fatty acid

    Has 1 C=C bond
  • Unsaturated fatty acid
    Has more than 1 C=C bond
  • Triglyceride formation
    1. 1 glycerol bonded to 3 fatty acids, via a condensation reaction between —COOH group of the acid and —OH group of glycerol
    2. A covalent bond forms, called an ester bond
  • Triglycerides
    • An energy source- can be broken down in resp. to generate ATP
    • Insulation- adipose tissue storage, electric and heat insulator
    • Energy store- insoluble in water so store without affecting w.p.
    • Buoyancy- fat is less dense than water so helps aquatic mammals keep afloat
    • Protection- have fat around delicate organs to act as shock absorber
  • Phospholipids
    • Same structure as triglyceride but one fatty acid replaced with phosphate group
    • Condensation reaction between an OH group on a phosphoric acid molecule and one of 3 -OH groups on glycerol form ester bond
    • Phosphate group is negative so hydrophilic but fatty acids is positive so hydrophobic so phospholipid is amphipathic
  • Cholesterol
    • Steroid alcohol or sterol- a type of lipid which is not made from glycerol or fatty acids
    • Consists of 4 carbon rings or isoprene units
    • Small and hydrophobic
    • Mainly made in liver in animals, plants have cholesterol derivative- stigmasterol
    • Steroid hormones, testosterone and oestrogen and vitamin D are made from cholesterol