Sensitisation is an increase in response following repeated exposure to the stimulus.
Desensitisation is a decrease of a previously sensitized response following repeated exposure to the stimulus.
Like habituation, but to a previously sensitized stimulus, desensitisation could lead to habituation if the stimulus becomes fully neutral. To be effective it must be gradual and not forceful.
Systematic desensitization is widely used in behaviour modification.
Spontaneous recovery is the recovery of a habituated response due to few presentations of stimuli or because of a strong extraneous stimulus.