Reactants in the same phase of matter (like aqueoussolutions), collide due to the natural, unpredictable motion of molecules, wherein gentlestirring mixes them more thoroughly and therefore reactsfaster.
Reactants in a differentphase of matter, contact only at the interfacebetweenphases, therefore vigorousstirring or grinding may be needed to produce collisions, thereby producing reactions– albeit at a slower rate.
Interface means the surface where two different materials touch each other. Like if you pour oil into water, the interface is the surface where the oil and water meet.
Temperature
Molecules must collide with enoughenergy.
Hightemperatures give molecules highkinetic energy, increasingcollision frequency, and thereby increasingreaction rate.
Lowtemperatures give molecules lowkineticenergy, decreasingcollisionfrequency, and thereby decreasingreactionrate.