If we heat hydrated copper sulfate(which is blue), then it reacts to form anhydrous copper sulfate, which is white. The reaction also produces water. Because we are heating this, we are putting energy in and this means the forward reaction is endothermic. If we take anhydrous copper sulfate and add the water back, then the reaction reverses. Here, energy is released and the reaction gets hot, this tell us the reverse reaction is exothermic. hydrated copper sulfate ⇌ anhydrous copper sulfate + water