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Physical Metallurgy
kinetics of crystalisation
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Created by
Bonolo Chidi
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Cards (5)
Gibbs
free energy
Determines spontaneity of reactions in
closed
systems (no transfer of
mass
)
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Gibbs free energy conditions
ΔG =
0
(
equilibrium
)
ΔG >
0
(spontaneous in the
opposite
direction)
ΔG <
0
(
proceed spontaneously
)
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Gibbs free energy
It is affected by the particle's surface (
positive
) and internal (
negative
) energies
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Effect of Temperature
1. T_m =
equilibrium solidification
temperature
2. H_f = latent heat of
fusion
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Heterogenous Nucleation
1. Ɣ_SL =
solid-liquid
2. Ɣ_SI =
solid surface
3. Ɣ_IL =
liquid surface
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