When substances are heated, the particles absorb thermal energy which is converted into kinetic energy, heating a solid causes its particles to vibrate more and as the temperature increases, they vibrate so much that the solid expands until the structure breaks and the solid melts, on further heating, the now liquid substance expands more and some particles at the surface gain sufficient energy to overcome the intermolecular forces and evaporate, when the b.p. temperature is reached, all the particles gain enough energy to escape and the liquids boils