Aldehydes and ketones

Cards (8)

  • The general formula for aldehydes is R-CHO, where R can be any hydrocarbon chain.
  • Aldehydes have their carbonyl group at the end of the carbon chain unlike ketones
  • The reducing agent used to reduce aldehydes and ketones is NaBH4
  • If an unsymmetrical ketones are reduced it will produce optical isomers and as there is an equal chance for the hydride ion to attack above and below the bond a racemic mixture will be produced
  • Undergo nucleophilic addition with cyanide ions to form hydroxynitriles
  • Reduction of an aldehyde:
    NaBH4 and water
    A) supplied by NaBH4
    B) supplied by water
  • Nucleophilic addition of aldehydes/ketones requires
    Reagents:
    KCN
    dilute H2SO4
  • Draw the mechanism for the reduction of ethanone or ethanol with KCN
    .