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1. physical chemistry
chapter 1: atomic structure
1.5 more about electron arrangements in atoms
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Deryn Daley
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shells can be called
main
energy levels
the maximum number of electrons in each main level can be given by the formula
2n^2
where n is the number of the
energy level
main energy levels can be divided up into
sublevels
called
s
,
p
,
d
, and
f
electrons are considered to be a
cloud
of
negative
charge
an electron fills a
volume
in
space
called its
atomic orbital
s
orbital
p
orbitals
orbitals:
s
p
d
f
the
orbital shapes
represent a volume of space in which there's a
95
% probability of finding an electron
first
main energy level:
one s
orbital
second
main energy level:
one s
orbital
three p orbitals
third
main energy level:
one s
orbital
three p
orbitals
five d
orbitals
fourth
main energy levels:
one s
orbital
three p
orbitals
five d
orbitals
seven f
orbitals
any single atomic orbital can hold a maximum of
2
electrons
s
orbitals can hold up to
2
electrons
p
orbitals can hold up to
6
electrons
d
orbitals can hold up to
10
electrons
f
electrons can hold up to
14
electrons
electrons have a property called
spin
two electrons in the same orbital must have
opposite
spins
rules for allocating electrons:
atomic orbitals of
lower
energy are filled first
atomic orbitals of the same energy fill singly before
pairing
starts because electrons
repel
each other
no atomic orbital can hold more than
two
electrons
the
4s
orbital fills before the
3d
orbital because it is of
lower
energy